Sebastien Paul

Professeur

Catalyse Hétérogène

Bâtiment : ECL

Bureau : C010

Téléphone : (+33) 03 20 33 54 57

Fax : (+33) 03 20 33 54 99

Email : Cette adresse e-mail est protégée contre les robots spammeurs. Vous devez activer le JavaScript pour la visualiser.

Adresse : Université Lille 1
Cité Scientifique, Bâtiment C3
59650 Villeneuve d'Ascq Cedex
France

Formation

  • Doctorat en Génie des Procédés Industriels de l’Université de Technologie de Compiègne
    • Sujet : Cinétique et mise en œuvre de catalyseurs pour l’oxydation de l’isobutane en acide méthacrylique. Directeur de thèse : Pr. Dominique VANHOVE
  • D.E.A. en Génie des Procédés Industriels de l’Université de Technologie de Compiègne.
  • Diplôme d’Ingénieur Chimiste de l’Ecole Nationale Supérieure de Chimie de Lille.

Thématique de recherche

Contribution au développement de procédés plus propres, plus sûrs et plus compétitifs pour l’industrie chimique.

Réactions étudiées

  • Oxydation sélective des alcanes légers :
    • valorisation du propane en propylène et acide acrylique
    • valorisation de l’isobutane en acide méthacrylique
  • Oxydation sélective du propylène en acroléine
  • Valorisation du glycérol en acroléine

Démarche

  • Etude cinétique
  • Etude des mécanismes réactionnels
  • Etude de réactivité
  • Développement de réacteurs structurés (plaques, mousses…)
    • Dépôts sur supports métalliques
    • Caractérisation

Activités de recherche en cours

  • Participation à l’ANR MILLICAT : Dépôts catalytiques pour réacteurs micro et millistructurés
  • Participation à l’ANR NG2M : Nouvelles Générations de Matériaux Moléculaires pour l’oxydation des alcanes légers
  • Co-encadrement de la thèse CNRS-Région de Benjamin Katryniok : « Nouvelle voie de synthèse d’un grand intermédiaire chimique : l’acroléine »
  • Contrats industriels divers

Collaborations internationales

  • Institut de Chimie Inorganique de l’Université Fédérale de Rio de Janeiro, Brésil (Pr. J.G. Eon)
  • Département de Génie Chimique de l’Université de Sichuan, Chine (Pr. Chu Wei)

Publications

Dans la base de données : 58
  • 2017

  • Al-doped SBA-15 catalysts for low-temperature dehydration of 1,3-butanediol into butadiene.
    Pera-Titus Marc, Jing Fangli, Katryniok Benjamin, Paul Sebastien, Fang Lin, Liebens Armin, Shen Ming, Hu Bingwen, Dumeignil Franck.
    ChemCatChem, vol. 9(2), pg. 258-262 (2017) DOI
     
  • Oxidation of but-3-en-1,2-diol: Green access to hydroxymethionine intermediate.
    Grasset F., Rey P., Bellière-Baca V., Araque M., Paul S., Dumeignil F., Wojcieszak R., Katryniok B.
    Catalysis Today, vol. 279, pg. 164-167 (2017) DOI
     
  • 2016

  • Steam reforming, partial oxidation and oxidative steam reforming for hydrogen production from ethanol over cerium nickel based oxyhydride catalyst.
    Pirez Cyril, Fang Wenhao, Capron Mickaël, Paul Sébastien, Jobic Hervé, Dumeignil Franck, Jalowiecki-Duhamel Louise.
    Applied Catalysis A: General, vol. 518, pg. 78-86 (2016) DOI
     
  • Role of Promoters on the Acrolein Ammoxidation Performances of BiMoO x.
    Ghalwadkar Ajay, Katryniok Benjamin, Paul Sébastien, Mamede Anne-Sophie, Dumeignil Franck.
    Journal of the American Oil Chemists<#039; Society, vol. 93 (1), pg. 431-443 (2016) DOI
     
  • The Role of Steric Effects and Acidity in the Direct Synthesis ofiso-Paraffins from Syngas on Cobalt Zeolite Catalysts.
    Subramanian Vijayanand, Zholobenko Vladimir L., Cheng Kang, Lancelot Christine, Heyte Svetlana, Thuriot Joelle, Paul Sébastien, Ordomsky Vitaly V., Khodakov Andrei Y.
    ChemCatChem, vol. 8, pg. 380-389 (2016) DOI
     
  • First catalytic asymmetric hydrogenation of quinoxaline-2-carboxylates.
    Maj Anna M., Heyte Svetlana, Araque Marcia, Dumeignil Franck, Paul Sébastien, Suisse Isabelle, Agbossou-Niedercorn Francine.
    Tetrahedron, vol. 72, pg. 1375-1380 (2016) DOI
     
  • Nanoreactors: An Efficient Tool To Control the Chain-Length Distribution in Fischer–Tropsch Synthesis.
    Subramanian Vijayanand, Cheng Kang, Lancelot Christine, Heyte Svetlana, Paul Sébastien, Moldovan Simona, Ersen Ovidiu, Marinova Maya, Ordomsky Vitaly V., Khodakov Andrei Y.
    ACS Catalysis, pg. 1785-1792 (2016) DOI
     
  • Novel direct amination of glycerol over heteropolyacid-based catalysts.
    Safariamin M., Paul S., Moonen K., Ulrichts D., Dumeignil F., Katryniok B.
    Catal. Sci. Technol., vol. 6, pg. 2129-2135 (2016) DOI
     
  • Effects of co-feeding with nitrogen-containing compounds on the performance of supported cobalt and iron catalysts in Fischer–Tropsch synthesis.
    Ordomsky Vitaly V., Carvalho Alexandre, Legras Benoit, Paul Sébastien, Virginie Mirella, Sushkevich Vitaly L., Khodakov Andrei Y.
    Catalysis Today, vol. 275, pg. 84-93 (2016) DOI
     
  • Catalytic Conversion of Alcohols into Carboxylic Acid Salts in Water: Scope, Recycling, and Mechanistic Insights.
    Zhang Lei, Nguyen Duc Hanh, Raffa Guillaume, Trivelli Xavier, Capet Frédéric, Desset Simon, Paul Sébastien, Dumeignil Franck, Gauvin Régis M.
    ChemSusChem, vol. 9 (12), pg. 1413-1423 (2016) DOI
     
  • Efficient deuterium labelling of alcohols in deuterated water catalyzed by ruthenium pincer complexes.
    Zhang Lei, Nguyen Duc Hanh, Raffa Guillaume, Desset Simon, Paul Sébastien, Dumeignil Franck, Gauvin Régis M.
    Catalysis Communications, vol. 84, pg. 67-70 (2016) DOI
     
  • Acceptorless dehydrogenative coupling of alcohols catalysed by ruthenium PNP complexes: Influence of catalyst structure and of hydrogen mass transfer.
    Zhang Lei, Raffa Guillaume, Nguyen Duc Hanh, Swesi Youssef, Corbel-Demailly Louis, Capet Frédéric, Trivelli Xavier, Desset Simon, Paul Sébastien, Paul Jean-François, Fongarland Pascal, Dumeignil Franck, Gauvin Régis M.
    Journal of Catalysis, vol. 340, pg. 331-343 (2016) DOI
     
  • Advanced functionalized Mg2AlNiXHZOY nano-oxyhydrides ex-hydrotalcites for hydrogen production from oxidative steam reforming of ethanol.
    Fang Wenhao, Pirez Cyril, Paul Sébastien, Jiménez-Ruiz Mónica, Jobic Hervé, Dumeignil Franck, Jalowiecki-Duhamel Louise.
    International Journal of Hydrogen Energy, vol. 41, pg. 15443-15452 (2016) DOI
     
  • Direct dehydration of 1,3-butanediol into butadiene over aluminosilicate catalysts.
    Jing F., Katryniok B., Araque M., Wojcieszak R., Capron M., Paul S., Daturi M., Clacens J.-M., De Campo F., Liebens A., Dumeignil F., Pera-Titus M.
    Catal. Sci. Technol., vol. 6, pg. 5830-5840 (2016) DOI
     
  • Role of Crystalline Structure in Allyl Alcohol Selective Oxidation over Mo3VOxComplex Metal Oxide Catalysts.
    Murayama Toru, Katryniok Benjamin, Heyte Svetlana, Araque Marcia, Ishikawa Satoshi, Dumeignil Franck, Paul Sébastien, Ueda Wataru.
    ChemCatChem, vol. 8, pg. 2415-2420 (2016) DOI
     
  • 2015

  • Structural Evolution under Reaction Conditions of Supported (NH4)3HPMo11VO40 Catalysts for the Selective Oxidation of Isobutane.
    Jing Fangli, Katryniok Benjamin, Bordes-Richard Elisabeth, Dumeignil Franck, Paul Sébastien.
    Catalysts, vol. 5, pg. 460-477 (2015) DOI
     
  • Highly loaded well dispersed stable Ni species in NiXMg2AlOY nanocomposites: Application to hydrogen production from bioethanol.
    Fang Wenhao, Paul Sébastien, Capron Mickaël, Biradar Ankush V., Umbarkar Shubhangi B., Dongare Mohan K., Dumeignil Franck, Jalowiecki-Duhamel Louise.
    Applied Catalysis B: Environmental, vol. 166-167, pg. 485-496 (2015) DOI
     
  • The role of carbon atoms of supported iron carbides in Fischer–Tropsch synthesis.
    Ordomsky V. V., Legras B., Cheng K., Paul S., Khodakov A. Y.
    Catal. Sci. Technol., vol. 5, pg. 1433-1437 (2015) DOI
     
  • Effect of oxomolybdate species dispersion on direct methanol oxidation to dimethoxymethane over MoOx/TiO2catalysts.
    Faye Jérémy, Capron Mickaël, Takahashi Atsushi, Paul Sébastien, Katryniok Benjamin, Fujitani Tadahiro, Dumeignil Franck.
    Energy Science < Engineering, vol. 3, pg. 115-125 (2015) DOI
     
  • High yield lactic acid selective oxidation into acetic acid over a Mo-V-Nb mixed oxide catalyst.
    Lomate Samadhan, Katryniok Benjamin, Dumeignil Franck, Paul Sébastien.
    Sustainable Chemical Processes, vol. 3 (2015) DOI
     
  • Pore size effects in high-temperature Fischer–Tropsch synthesis over supported iron catalysts.
    Cheng Kang, Virginie Mirella, Ordomsky Vitaly V., Cordier Catherine, Chernavskii Petr A., Ivantsov Mikhail I., Paul Sébastien, Wang Ye, Khodakov Andrei Y.
    Journal of Catalysis, vol. 328, pg. 139-150 (2015) DOI
     
  • REALCAT: A New Platform to Bring Catalysis to the Lightspeed.
    Paul Sébastien, Heyte Svetlana, Katryniok Benjamin, Garcia-Sancho Cristina, Maireles-Torres Pedro, Dumeignil Franck.
    Oil < Gas Science and Technology – Revue d’IFP Energies nouvelles, vol. 70, pg. 455-462 (2015) DOI
     
  • Sodium-promoted iron catalysts prepared on different supports for high temperature Fischer–Tropsch synthesis.
    Cheng Kang, Ordomsky Vitaly V., Legras Benoit, Virginie Mirella, Paul Sébastien, Wang Ye, Khodakov Andrei Y.
    Applied Catalysis A: General, vol. 502, pg. 204-214 (2015) DOI
     
  • Recent developments in maleic acid synthesis from bio-based chemicals.
    Wojcieszak Robert, Santarelli Francesco, Paul Sébastien, Dumeignil Franck, Cavani Fabrizio, Gonçalves Renato V.
    Sustainable Chemical Processes, vol. 3, pg. 1-11 (2015) DOI
     
  • Biomass-derived Platform Molecules Upgrading through Catalytic Processes: Yielding Chemicals and Fuels.
    Dumeignil Franck, Capron Mickaël, Katryniok Benjamin, Wojcieszak Robert, Löfberg Axel, Girardon Jean-Sébastien, Desset Simon, Araque-Marin Marcia, Jalowiecki-Duhamel Louise, Paul Sébastien.
    Journal of the Japan Petroleum Institute, vol. 58, pg. 257-273 (2015) DOI
     
  • 2014

  • Catalytic selective oxidation of isobutane to methacrylic acid on supported (NH4)3HPMo11VO40 catalysts.
    Jing Fangli, Katryniok Benjamin, Dumeignil Franck, Bordes-Richard Elisabeth, Paul Sébastien.
    Journal of Catalysis, vol. 309, pg. 121-135 (2014) DOI
     
  • Hydrogen production from bioethanol catalyzed by NiXMg2AlOY ex-hydrotalcite catalysts.
    Fang Wenhao, Paul Sébastien, Capron Mickaël, Dumeignil Franck, Jalowiecki-Duhamel Louise.
    Applied Catalysis B: Environmental, vol. 152-153, pg. 370-382 (2014) DOI
     
  • Reply to the Letter to the Editor concerning the comments of M.A. Banares and M.O. Guerrero-Pérez to the article “Glycerol conversion to acrylonitrile by consecutive dehydration over WO3/TiO2 and ammoxidation over Sb-(Fe,V)-O”.
    Liebig Carsten, Paul Sébastien, Katryniok Benjamin, Guillon Cyrille, Couturier Jean-Luc, Dubois Jean-Luc, Dumeignil Franck, Hoelderich Wolfgang F.
    Applied Catalysis B: Environmental, vol. 148-149, pg. 604-605 (2014) DOI
     
  • The direct ethanol conversion to hydrocarbons over pt-containing catalysts.
    Tsodikov M V , Murzin V Y , Chistyakov A V , Yandieva F A , Gubanov M A , Zharova P A , Shapovalov S S , Tikhonova O G , Pasynskii A A , Paul S , Dumeignil F .
    Chemical Engineering Transactions, vol. 37, pg. 583-588 (2014) DOI
     
  • Combined Conversion of ethanol and vegetable oils to hydrocarbons.
    Chistyakov A V , Gubanov , M A , Zharova P A , Tsodikov M V , Paul S , Dumeignil F .
    Chemical Engineering Transactions, vol. 37, pg. 547 (2014) DOI
     
  • Catalytic selective oxidation of isobutane over Csx(NH4)3−xHPMo11VO40mixed salts.
    Jing Fangli, Katryniok Benjamin, Dumeignil Franck, Bordes-Richard Elisabeth, Paul Sébastien.
    Catalysis Science < Technology, vol. 4, pg. 2938 (2014) DOI
     
  • Support effects in high temperature Fischer-Tropsch synthesis on iron catalysts.
    Cheng K., Ordomsky V.V., Virginie M., Legras B., Chernavskii P.A., Kazak V.O., Cordier C., Paul S., Wang Ye, Khodakov A.Y.
    Applied Catalysis A: General, vol. 488, pg. 66-77 (2014) DOI
     
  • Glycerol-Derived Renewable Polyglycerols: A Class of Versatile Chemicals of Wide Potential Application.
    Ciriminna Rosaria, Katryniok Benjamin, Paul Sébastien, Dumeignil Franck, Pagliaro Mario.
    Organic Process Research < Development, vol. 19 (7), pg. 748-754 (2014) DOI
     
  • 2013

  • Recent developments in the field of catalytic dehydration of glycerol to acrolein.
    Katryniok Benjamin, Paul Sebastien, Dumeignil Franck.
    ACS Catalysis, vol. 3(8), pg. 1819-1834 (2013) DOI
     
  • Improvement of the catalytic performance of supported (NH4)3HPMo11VO40 catalysts in isobutane selective oxidation.
    Jing Fangli, Katryniok Benjamin, Bordes-Richard Elisabeth, Paul Sébastien.
    Catalysis Today, vol. 203, pg. 32-39 (2013) DOI
     
  • Glycerol conversion to acrylonitrile by consecutive dehydration over WO3/TiO2 and ammoxidation over Sb-(Fe,V)-O.
    Liebig Carsten, Paul Sébastien, Katryniok Benjamin, Dumeignil Franck, Hoelderich Wolfgang F.
    Applied Catalysis B: Environmental, vol. 132-133, pg. 170-182 (2013) DOI
     
  • Room Temperature H2 Production from Ethanol over CeNiXHZOY Nano-Oxyhydride Catalysts.
    Fang Wenhao, Pirez Cyril, Paul Sébastien, Capron Mickaël, Jobic Hervé, Dumeignil Franck, Jalowiecki-Duhamel Louise.
    ChemCatChem, vol. 5(8), pg. 2207-2216 (2013) DOI
     
  • Selective Oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over Intercalated Vanadium Phosphate Oxides.
    Grasset Fabien, Katryniok Benjamin, Paul Sebastien, Nardello-Rataj Veronique, Pera-Titus Marc, Clacens Jean-Marc, Decampo Floryan, Dumeignil Franck Yves.
    RSC Advances, vol. 3, pg. 9942-9958 (2013) DOI
     
  • Synthesis of Pyruvic Acid by Vapour Phase Catalytic Oxidative Dehydrogenation of Lactic Acid.
    Lomate Samadhan, Bonotte Thomas, Paul Sébastien, Dumeignil Franck, Katryniok Benjamin.
    Journal of Molecular Catalysis A: General, vol. 377, pg. 123-128 (2013) DOI
     
  • Ammoxidation of allyl alcohol – a sustainable route to acrylonitrile.
    Guillon Cyrille, Liebig Carsten, Paul Sebastien, Mamede Anne-Sophie, Holderich Wolfgang F., Dumeignil Franck Yves, Katryniok Benjamin.
    Green Chemistry, vol. 15 (11), pg. 3015-3019 (2013) DOI
     
  • 2012

  • Regeneration of Silica-Supported Silicotungstic Acid as a Catalyst for the Dehydration of Glycerol.
    Katryniok Benjamin, Paul Sébastien, Capron Mickaël, Bellière-Baca Virginie, Rey Patrick, Dumeignil Franck.
    ChemSusChem, vol. 5 (7), pg. 1298-1306 (2012) DOI
     
  • Ce-Ni mixed oxide as efficient catalyst for H2 production and nanofibrous carbon material from ethanol in presence of water.
    Duhamel-Jalowiecki Louise, Fang Wenhao, Pirez Cyril, Capron Michaël, Paul Sébastien, Raja Thirumalaiswamy, Dhepe Paresh L., Dumeignil Franck.
    RSC Advances, vol. 2, pg. 9626-9634 (2012) DOI
     
  • 2011

  • Synthesis and characterization of zirconia-grafted SBA-15 nanocomposites.
    Katryniok Benjamin, Paul Sébastien, Capron Mickaël, Royer Sébastien, Lancelot Christine, Jalowiecki-Duhamel Louise, Bellière-Baca Virginie, Rey Patrick, Dumeignil Franck.
    Journal of Materials Chemistry, vol. 21, pg. 8159 (2011) DOI
     
  • Selective catalytic oxidation of glycerol: perspectives for high value chemicals.
    Katryniok Benjamin, Kimura Hiroshi, Skrzyńska Elżbieta, Girardon Jean-Sébastien, Fongarland Pascal, Capron Mickaël, Ducoulombier Rémy, Mimura Naoki, Paul Sébastien, Dumeignil Franck.
    Green Chemistry, vol. 13, pg. 1960 (2011) DOI
     
  • Selective conversion of {Mo132} Keplerate ion into 4-electron reduced crown-capped Keggin derivative [Te5Mo15O57]8−. A key intermediate to single-phase M1 multielement MoVTeO light-alkanes oxidation catalyst.
    Canioni Romain, Marchal-Roch Catherine, Leclerc-Laronze Nathalie, Haouas Mohamed, Taulèlle Francis, Marrot Jérôme, Paul Sebastien, Lamonier Carole, Paul Jean-François, Loridant Stéphane, Millet Jean-Marc M., Cadot Emmanuel.
    Chemical Communications, vol. 47, pg. 6413 (2011) DOI
     
  • Coating of structured catalytic reactors by plasma assisted polymerization of tetramethyldisiloxane.
    Essakhi Adil, Mutel Brigitte, Supiot Philippe, Löfberg Axel, Paul Sébastien, Courtois Véronique Le, Meille Valérie, Pitault Isabelle, Bordes-Richard Elisabeth.
    Polymer Engineering < Science, vol. 51, pg. 940-947 (2011) DOI
     
  • Materials chemistry for catalysis: Coating of catalytic oxides on metallic foams.
    Essakhi A., Löfberg A., Paul S., Mutel B., Supiot P., Le Courtois V., Rodriguez P., Meille V., Bordes-Richard E.
    Microporous and Mesoporous Materials, vol. 140, pg. 81-88 (2011) DOI
     
  • Use of catalytic oxidation and dehydrogenation of hydrocarbons reactions to highlight improvement of heat transfer in catalytic metallic foams.
    Löfberg A., Essakhi A., Paul S., Swesi Y., Zanota M.-L., Meille V., Pitault I., Supiot P., Mutel B., Le Courtois V., Bordes-Richard E.
    Chemical Engineering Journal, vol. 176-177, pg. 49-56 (2011) DOI
     
  • Catalytic coatings for structured supports and reactors: VOx/TiO2 catalyst coated on stainless steel in the oxidative dehydrogenation of propane.
    Löfberg Axel, Giornelli Thierry, Paul Sébastien, Bordes-Richard Elisabeth.
    Applied Catalysis A: General, vol. 391, pg. 43-51 (2011) DOI
     
  • From Materials Science to Catalysis: Influence of the Coating of 2D- and 3D-Inserts on the Catalytic Behaviour of VOx/TiO2 in Oxidative Dehydrogenation of Propane.
    Essakhi A., Löfberg A., Paul S., Supiot P., Mutel B., Courtois V., Bordes-Richard E.
    Topics in Catalysis, vol. 54, pg. 698-707 (2011) DOI
     
  • The Future of Glycerol: 2nd Edition. By Mario Pagliaro and Michele Rossi.
    Katryniok Benjamin, Paul Sébastien, Dumeignil Franck.
    ChemSusChem, vol. 4, pg. 665-665 (2011) DOI
     
  • 2010

  • A long-life catalyst for glycerol dehydration to acrolein.
    Katryniok Benjamin, Paul Sébastien, Capron Mickaël, Lancelot Christine, Bellière-Baca Virginie, Rey Patrick, Dumeignil Franck.
    Green Chemistry, vol. 12, pg. 1922 (2010) DOI
     
  • Keggin-type H4PVMo11O40-based catalysts for the isobutane selective oxidation.
    Paul Sébastien, Chu Wei, Sultan Manzoor, Bordes-Richard Elisabeth.
    Science China Chemistry, vol. 53, pg. 2039-2046 (2010) DOI
     
  • Highly efficient catalyst for the decarbonylation of lactic acid to acetaldehyde.
    Katryniok Benjamin, Paul Sébastien, Dumeignil Franck.
    Green Chemistry, vol. 12, pg. 1910 (2010) DOI
     
  • Glycerol dehydration to acrolein in the context of new uses of glycerol.
    Katryniok Benjamin, Paul Sébastien, Bellière-Baca Virginie, Rey Patrick, Dumeignil Franck.
    Green Chemistry, vol. 12, pg. 2079 (2010) DOI
     
  • Oxidative dehydrogenation of propane under steady-state and transient regimes over alumina-supported catalysts prepared from mixed V2W4O4−19 hexametalate precursors.
    Paul Sébastien, Berrier Elise, França Marcia Cristina Kaezer, Eon Jean-Guillaume.
    Journal of Natural Gas Chemistry, vol. 19, pg. 123-133 (2010) DOI
     
  • 2009

  • Towards the Sustainable Production of Acrolein by Glycerol Dehydration.
    Katryniok Benjamin, Paul Sébastien, Capron Mickaël, Dumeignil Franck.
    ChemSusChem, vol. 2, pg. 719-730 (2009) DOI
     
  • 2008

  • Investigation of H2 staging effects on CO conversion and product distribution for Fischer–Tropsch synthesis in a structured microchannel reactor.
    Guillou L., Paul S., Le Courtois V.
    Chemical Engineering Journal, vol. 136, pg. 66-76 (2008) DOI