Rose-Noelle Vannier

Professeur à l'ENSCL

Axe Chimie du Solide

Bâtiment : C7

Bureau : 208

Téléphone : (+33) 03 20 43 65 83

Fax : (+33) 03 20 43 68 14

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Adresse : Ecole Nationale Supérieure de Chimie de Lille
Cité Scientifique, Bâtiment C7 - BP 90108
59652 Villeneuve d'Ascq Cedex
France

Activités de recherche

Responsable de l’axe  « Chimie du Solide » et de l’équipe « Matériaux oxyde pour l’énergie » .

Nos recherches portent sur la mise en évidence et la caractérisation de nouveaux conducteurs par ions oxyde. Sous la forme de céramiques denses, ces matériaux pourront être développés comme membrane dense dans les piles à combustible ou dans les électrolyseurs à haute température, pour la séparation électrochimique de l'oxygène de l'air, comme capteur, comme réacteur à membrane dense pour la catalyse. Poreuses avec une contribution électronique en plus de la conduction ionique, ces céramiques seront utilisées comme matériaux d’électrode. Une large part de nos recherches est consacrée à la compréhension des mécanismes de diffusion des ions oxyde dans ces céramiques, de l’échelle microscopique à l’échelle macroscopique.

Pour caractériser ces matériaux, nous faisons appel à la diffraction des rayons X, à la spectroscopie de diffusion Raman, à la microscopie électronique (MET, MEB, microsonde de Castaing), aux grands instruments (diffraction des neutrons, rayonnement synchrotron, EXAFS, XANES), aux techniques courantes d'analyses thermiques (ATG, ATD, DSC, dilatométrie), à la spectrométrie d'impédance, la voltamétrie, l’échange isotopique combiné au SIMS, la RMN de l’oxygène 17, ….  

Nos recherches reposent sur de nombreuses collaborations, avec notamment, le CEA, EDF, PSA, l’IMN-Nantes, le LECIME ENSC-Paris, le LEPMI-Grenoble, l’IRCE-Lyon, le SCR-Rennes, l’Ecole Centrale de Paris, le département matériaux de l’Imperial College de Londres, l’University College London,  l’Université de St-Andrews (Royaume-Uni), l’Université Technique de Varsovie (Pologne), l’Université de Craiova (Roumanie), l’Université de Twente (Pays-Bas), l’Université de Shanghai (Chine), l’Universidad Industrial de Santander en Colombie …

 

Doctorat : "Nouvelles phases d'Aurivillius conductrices bidimensionnelles par ions oxyde", soutenu à Lille le 5 février 1992, BDI CNRS-Région, sous la direction du Professeur Gaëtan Mairesse, Laboratoire de Cristallochimie et Physicochimie du Solide, UMR CNRS 8012.

 

HDR : "Matériaux de basse dimensionnalité, conducteurs par anions oxyde - Corrélation structure-propriétés", soutenue à Lille le 28 mai 1999.

 
2000-2001 : Bourse Marie Curie à l’Impérial College de Londres dans l’équipe du Professeur John Kilner, « Caractérisation des phénomènes de transport de l’oxygène dans les matériaux à base d’oxyde de bismuth par échange isotopique de l’oxygène », délégation d’un an au CNRS.

Activités d’enseignement

Professeur à l'Ecole Nationale Supérieure de Chimie de Lille

 

Ancienne élève de l'ENSCL (89), j'ai à cœur de transmettre mon savoir et mes compétences. Responsable du module « Chimie minérale », j'interviens dans le cycle ingénieur :

- Cours de chimie minérale et industrielle (1ère année),

- Cours de cristallochimie (1ère année);

- Cours sur les techniques d'analyses des solides (2ème année),

- Cours sur les matériaux fonctionnels pour l’énergie (3ème année et master 2),

- Encadrement d'un mini-projet de recherche (3ème année)

Publications

Dans la base de données : 68
  • 2017

  • Guerbet Reaction over Strontium-Substituted Hydroxyapatite Catalysts Prepared at Various (Ca+Sr)/P Ratios.
    Silvester Lishil, Lamonier Jean-François, Lamonier Carole, Capron Mickaël, Vannier Rose-Noëlle, Mamede Anne-Sophie, Dumeignil Franck.
    ChemCatChem, (2017) DOI
     
  • 2016

  • Active Mn species well dispersed on Ca2+ enriched apatite for total oxidation of toluene.
    Chlala D., Giraudon J.-M., Nuns N., Lancelot C., Vannier Rose-Noëlle, Labaki M., Lamonier J.-F.
    Applied Catalysis B: Environmental, vol. 184, pg. 87-95 (2016) DOI
     
  • Changes in structure and electrical conductivity of rare-earth titanate pyrochlores under highly reducing atmosphere.
    Cioatera N., Voinea E.A., Panaintescu E., Rolle A., Somacescu S., Spinu C.I., Vannier R.N.
    Ceramics International, vol. 42, pg. 1492-1500 (2016) DOI
     
  • Electrostatic spray deposition of Ca3Co4O9+δ layers to be used as cathode materials for IT-SOFC.
    Djurado E., Salaün A., Mignardi G., Rolle A., Burriel M., Daviero-Minaud S., Vannier R.N.
    Solid State Ionics, vol. 286, pg. 102-110 (2016) DOI
     
  • Ca3Co4O9+δ, a growing potential SOFC cathode material: Impact of the layer composition and thickness on the electrochemical properties.
    Rolle Aurélie, Mohamed Hussien Ahmed Abbas, Huo Da, Capoen Edouard, Mentré Olivier, Vannier Rose-Noëlle, Daviero-Minaud Sylvie, Boukamp Bernard A.
    Solid State Ionics, vol. 294, pg. 21-30 (2016) DOI
     
  • 2015

  • Sol–gel synthesis and characterization of silica supported nickel ferrite catalysts for dry reforming of methane.
    Benrabaa Rafik, Löfberg Axel, Guerrero Caballero Jesús, Bordes-Richard Elisabeth, Rubbens Annick, Vannier Rose-Noëlle, Boukhlouf Hamza, Barama Akila.
    Catalysis Communications, vol. 58, pg. 127-131 (2015) DOI
     
  • Benzaldehyde reduction over Cu-Al-O bimetallic oxide catalyst. Influence of pH during hydrothermal synthesis on the structural and catalytic properties.
    Haddad N., Saadi A., Löfberg A., Vannier R.N., Bordes-Richard E., Rabia C.
    Journal of Molecular Catalysis A: Chemical, vol. 396, pg. 207-215 (2015) DOI
     
  • Pure and Mn-doped La4SrTi5O17 layered perovskite as potential solid oxide fuel cell material: Structure and anodic performance.
    Périllat-Merceroz Cédric, Roussel Pascal, Huvé Marielle, Capoen Edouard, Rosini Sébastien, Gélin Patrick, Vannier Rose-Noëlle, Gauthier Gilles H.
    Journal of Power Sources, vol. 274, pg. 806-815 (2015) DOI
     
  • Bi4V2O11 and BITAVOX.20 coatings deposited by reactive magnetron sputtering.
    Dereeper E., Briois P., Vannier R.-N., Billard A.
    Materials Chemistry and Physics, vol. 153, pg. 9-16 (2015) DOI
     
  • Synthesis and characterization of LaNixCo1−xO3: Role of microstructure on magnetic properties.
    Chávez-Guerrero L., Medina-Lott B., Cienfuegos R.F., Garza-Navarro M.A., Vannier R.N., Ringuedé A., Hinojosa M., Cassir M.
    Journal of Rare Earths, vol. 33, pg. 277-281 (2015) DOI
     
  • Growth of Ca3Co4O9+δ thin film on sapphire substrate and CGO dense pellet by pulsed laser deposition. Structural, microstructural, surface and electrochemical characterizations.
    Chambrier M.H., Huo D., Thoréton V., Rolle A., Mamède A.S., Estradé S., Blach J.F., Pirovano C., Daviero-Minaud S., Roussel P., Peiró F., Vannier R.N.
    Solid State Ionics, vol. 273, pg. 13-17 (2015) DOI
     
  • Reactivity of ethanol over hydroxyapatite-based Ca-enriched catalysts with various carbonate contents.
    Silvester Lishil, Lamonier Jean-François, Faye Jérémy, Capron Mickaël, Vannier Rose-Noëlle, Lamonier Carole, Dubois Jean-Luc, Couturier Jean-Luc, Calais Christophe, Dumeignil Franck.
    Catal. Sci. Technol., vol. 5, pg. 2994-3006 (2015) DOI
     
  • Synthesis and properties of La0.05Ba0.95Ti1−xMyO3 (M=Mn, Ce) as anode materials for solid oxide fuel cells.
    Périllat-Merceroz Cédric, Roussel Pascal, Capoen Edouard, Rosini Sébastien, Gélin Patrick, Vannier Rose-Noëlle, Gauthier Gilles.
    Solid State Ionics, vol. 283, pg. 21-29 (2015) DOI
     
  • Search for Li-electrochemical activity and Li-ion conductivity among lithium bismuth oxides.
    Subban Chinmayee V., Rousse Gwenaëlle, Vannier Rose-Noëlle, Laberty-Robert Christel, Barboux Philippe, Tarascon Jean-Marie.
    Solid State Ionics, vol. 283, pg. 68-74 (2015) DOI
     
  • Preparation and characterization of p–n heterojunction CuBi2O4/CeO2 and its photocatalytic activities under UVA light irradiation.
    Elaziouti Abdelkader, Laouedj Nadjia, Bekka Ahmed, Vannier Rose-Noëlle.
    Journal of King Saud University - Science, vol. 27, pg. 120-135 (2015) DOI
     
  • 2014

  • Synthesis and characterization of La0.6Sr0.4Co0.8Fe0.2O3 films for Solid Oxide Fuel Cell cathodes.
    Dumaisnil K., Fasquelle D., Mascot M., Rolle A., Roussel P., Minaud S., Duponchel B., Vannier R.-N., Carru J.-C.
    Thin Solid Films, vol. 553, pg. 89-92 (2014) DOI
     
  • Structural, textural and acid–base properties of carbonate-containing hydroxyapatites.
    Silvester Lishil, Lamonier Jean-François, Vannier Rose-Noëlle, Lamonier Carole, Capron Mickaël, Mamede Anne-Sophie, Pourpoint Frédérique, Gervasini Antonella, Dumeignil Franck.
    Journal of Materials Chemistry A, vol. 2, pg. 11073-11090 (2014) DOI
     
  • Oxygen transport kinetics of the misfit layered oxide Ca3Co4O9+d.
    Thoréton Vincent, Hu Yang, Pirovano Caroline, Capoen Edouard, Nuns Nicolas, Mamede Anne-Sophie, Dezanneau Guilhem, Yoo Chun-Yul, Bouwmeester Henny J.M., Vannier Rose-Noelle.
    J. Mater. Chem. A, vol. 2, pg. 19717-19725 (2014) DOI
     
  • Oxide Ion Transport in Promising Cobaltites for SOC.
    Thoréton Vincent, Hu Y., Kehal I., Flandre X., Huo Da, Pirovano C., Rolle A., Capoen E., Nuns N., Mamede A.S., Dezanneau G., Vannier R.N.
    Procedia Engineering, vol. 98, pg. 115-120 (2014) DOI
     
  • Aminopolycarboxylate Bismuth(III)-Based Heterometallic Compounds as Single-Source Molecular Precursors for Bi4V2O11and Bi2CuO4Mixed Oxides.
    Bulimestru Ion, Shova Sergiu, Popa Nelea, Roussel Pascal, Capet Frederic, Vannier Rose-Noelle, Djelal Nora, Burylo Laurence, Wignacourt Jean-Pierre, Gulea Aurelian, Whitmire Kenton H.
    Chemistry of Materials, vol. 26, pg. 6092-6103 (2014) DOI
     
  • Oxide diffusion in innovative SOFC cathode materials.
    Hu Y., Thoréton V., Pirovano C., Capoen E., Bogicevic C., Nuns N., Mamede A.-S., Dezanneau G., Vannier R. N.
    Faraday Discuss., vol. 176, pg. 31-47 (2014) DOI
     
  • 2013

  • Structure, reactivity and catalytic properties of nanoparticles of nickel ferrite in the dry reforming of methane.
    Benrabaa R., Löfberg A., Rubbens A., Bordes-Richard E., Vannier R.N., Barama A.
    Catalysis Today, vol. 203, pg. 188-195 (2013) DOI
     
  • New insights on the structure and reducibility of 3D versus 2D La/Sr titanates for SOFC anodes.
    Périllat-Merceroz Cédric, Roussel Pascal, Huvé Marielle, Capoen Edouard, Vannier Rose-Noëlle, Gauthier Gilles.
    Solid State Ionics, vol. 247-248, pg. 76-85 (2013) DOI
     
  • A new deposition process for Cu(In,Ga)(S,Se)2 solar cells by one-step electrodeposition of mixed oxide precursor films and thermochemical reduction.
    Duchatelet A., Savidand G., Vannier R. N., Chassaing E., Lincot D.
    Journal of Renewable and Sustainable Energy, vol. 5, pg. 011203 (2013) DOI
     
  • Nanocrystalline, mesoporous NiO/Ce0.9Gd0.1O2−δ thin films with tuned microstructures and electrical properties: in situ characterization of electrical responses during the reduction of NiO.
    Müller Guillaume, Vannier Rose-Noëlle, Ringuedé Armelle, Laberty-Robert Christel, Sanchez Clément.
    Journal of Materials Chemistry A, vol. 1, pg. 10753 (2013) DOI
     
  • Optimization of MoSe2 formation for Cu(In,Ga)Se2-based solar cells by using thin superficial molybdenum oxide barrier layers.
    Duchatelet A., Savidand G., Vannier R.N., Lincot D.
    Thin Solid Films, vol. 545, pg. 94-99 (2013) DOI
     
  • 2012

  • Structural, Textural and Acid–Base Properties of Nano-Sized NiFe2O4 Spinel Catalysts.
    Benrabaa R., Boukhlouf H., Barama S., Bordes-Richard E., Vannier R. N., Barama A.
    Catalysis Letters, vol. 142, pg. 42-49 (2012) DOI
     
  • Nickel ferrite spinel as catalyst precursor in the dry reforming of methane: Synthesis, characterization and catalytic properties.
    Benrabaa Rafik, Boukhlouf Hamza, Löfberg Axel, Rubbens Annick, Vannier Rose-Nöelle, Bordes-Richard Elisabeth, Barama Akila.
    Journal of Natural Gas Chemistry, vol. 21 (5), pg. 595-604 (2012) DOI
     
  • Gadolinia-doped ceria mixed with alkali carbonates for SOFC applications: II – An electrochemical insight.
    Benamira M., Ringuedé A., Hildebrandt L., Lagergren C., Vannier R.-N., Cassir M.
    International Journal of Hydrogen Energy, vol. 37, pg. 19371-19379 (2012) DOI
     
  • A Comprehensive Scenario of the Crystal Growth of γ-Bi2MoO6Catalyst during Hydrothermal Synthesis.
    Kongmark Chanapa, Coulter Rachel, Cristol Sylvain, Rubbens Annick, Pirovano Caroline, Löfberg Axel, Sankar Gopinathan, van Beek Wouter, Bordes-Richard Elisabeth, Vannier Rose-Noëlle.
    Crystal Growth < Design, vol. 12 (12), pg. 5994-6003 (2012) DOI
     
  • Enhanced ionic conductivity of Sm, Gd-doped ceria induced by modification of powder synthesis procedure.
    Cioateră N., Pârvulescu V., Rolle A., Vannier R.N.
    Ceramics International, vol. 38, pg. 5461-5468 (2012) DOI
     
  • 2011

  • Lamellar Titanates: A Breakthrough in the Search for New Solid Oxide Fuel Cell Anode Materials Operating on Methane.
    Périllat-Merceroz Cédric, Roussel Pascal, Vannier Rose-Noëlle, Gélin Patrick, Rosini Sébastien, Gauthier Gilles.
    Advanced Energy Materials, vol. 1, pg. 573-576 (2011) DOI
     
  • Effect of the dopant nature on the conductivity of oxygen overstoichiometric oxyapatites with controlled microstructures.
    Guillot Stéphanie, Beaudet-Savignat Sophie, Lambert Sébastien, Roussel Pascal, Vannier Rose-Noelle.
    Solid State Ionics, vol. 185, pg. 18-26 (2011) DOI
     
  • Local relaxation in lanthanum silicate oxyapatites by Raman scattering and MAS-NMR.
    Guillot Stéphanie, Beaudet-Savignat Sophie, Lambert Sébastien, Roussel Pascal, Tricot Gregory, Vannier Rose-Noelle, Rubbens Annick.
    Journal of Raman Spectroscopy, vol. 42, pg. 1455-1461 (2011) DOI
     
  • Synthesis and ion conductivity of (Bi2O3)0.75(Dy2O3)0.25 ceramics with grain sizes from the nano to the micro scale.
    Li Rong, Zhen Qiang, Drache Michel, Rubbens Annick, Estournes Claude, Vannier Rose-Noëlle.
    Solid State Ionics, vol. 198, pg. 6-15 (2011) DOI
     
  • Red-ox behaviour in the La0.6Sr0.4CoO3±δ-CeO2 system.
    Konysheva Elena Yu., Francis Stephen M., Irvine John T. S., Rolle Aurélie, Vannier Rose-Noelle.
    Journal of Materials Chemistry, vol. 21, pg. 15511 (2011) DOI
     
  • Gadolinia-doped ceria mixed with alkali carbonates for solid oxide fuel cell applications: I. A thermal, structural and morphological insight.
    Benamira M., Ringuedé A., Albin V., Vannier R.-N., Hildebrandt L., Lagergren C., Cassir M.
    Journal of Power Sources, vol. 196, pg. 5546-5554 (2011) DOI
     
  • Synthesis and Study of a Ce-Doped La/Sr Titanate for Solid Oxide Fuel Cell Anode Operating Directly on Methane.
    Périllat-Merceroz Cédric, Gauthier Gilles, Roussel Pascal, Huvé Marielle, Gélin Patrick, Vannier Rose-Noëlle.
    Chemistry of Materials, vol. 23, pg. 1539-1550 (2011) DOI
     
  • 2010

  • Synthesis of γ-Bi2MoO6 catalyst studied by combined high-resolution powder diffraction, XANES and Raman spectroscopy.
    Kongmark C., Martis V., Pirovano C., Löfberg A., van Beek W., Sankar G., Rubbens A., Cristol S., Vannier R.-N., Bordes-Richard E.
    Catalysis Today, vol. 157, pg. 257-262 (2010) DOI
     
  • Nanosized nickel ferrite catalysts for CO2 reforming of methane at low temperature: effect of preparation method and acid-base properties.
    Benrabaa R., Boukhlouf H., Bordes-Richard E., Vannier R.N., Barama A.
    Studies in Surface Science and Catalysis, vol. 175, pg. 301-304 (2010) DOI
     
  • La3TaO7 derivatives with Weberite structure type: Possible electrolytes for solid oxide fuel cells and high temperature electrolysers.
    Preux Nicolas, Rolle Aurélie, Merlin Cindy, Benamira Messaoud, Malys Marcin, Estournes Claude, Rubbens Annick, Vannier Rose-Noëlle.
    Comptes Rendus Chimie, vol. 13, pg. 1351-1358 (2010) DOI
     
  • Elaboration, by tape casting, and thermal characterization of a solid oxide fuel half-cell for low temperature applications.
    Bonhomme Claire, Beaudet-Savignat Sophie, Chartier Thierry, Pirovano Caroline, Vannier Rose-Noëlle.
    Materials Research Bulletin, vol. 45, pg. 491-498 (2010) DOI
     
  • CGO-based electrochemical catalysts for low temperature combustion of propene.
    Karoum R., Roche V., Pirovano C., Vannier Rose-Noelle, Billard A., Vernoux P.
    Journal of Applied Electrochemistry, vol. 40, pg. 1867-1873 (2010) DOI
     
  • Preparation mechanism of (Bi2O3)0.75(Dy2O3)0.25 nano-crystalline solid electrolyte.
    Li Rong, Zhen Qiang, Drache Michel, Rubbens Annick, Vannier Rose-Noëlle.
    Journal of Alloys and Compounds, vol. 494, pg. 446-450 (2010) DOI
     
  • Preparation and characterization of Bi0.75Er0.25O1.5 and Bi0.75Er0.125Y0.125O1.5 nanocrystalline ceramics by SPS.
    Li Rong, Zhen Qiang, Lu Xionggang, Drache Michel, Vannier Rose-Noëlle.
    Journal of Solid State Electrochemistry, vol. 15, pg. 1919-1926 (2010) DOI
     
  • 2009

  • Investigation of transport numbers in yttrium doped bismuth niobates.
    Małys M., Hołdynski M., Krok F., Wróbel W., Dygas J.R., Pirovano C., Vannier R.-N., Capoen E., Abrahams I.
    Journal of Power Sources, vol. 194, pg. 16-19 (2009) DOI
     
  • Low temperature electrochemical catalysts using a BITAVOX electrolyte.
    Karoum R., Pirovano C., Vannier R.N., Vernoux P., Billard A.
    Catalysis Today, vol. 146, pg. 359-366 (2009) DOI
     
  • Effect of strontium addition on europium-doped ceria properties.
    Cioateră N., Pârvulescu V., Rolle A., Vannier R.N.
    Solid State Ionics, vol. 180, pg. 681-687 (2009) DOI
     
  • Evidence of local defects in the oxygen excess apatite La9.67(SiO4)6O2.5 from high resolution neutron powder diffraction.
    Guillot Stéphanie, Beaudet-Savignat Sophie, Lambert Sébastien, Vannier Rose-Noelle, Roussel Pascal, Porcher Florence.
    Journal of Solid State Chemistry, vol. 182, pg. 3358-3364 (2009) DOI
     
  • Local environment in Ba2In2−xWxO5+3x/2 oxide ion conductors.
    Daviero-Minaud Sylvie, Rolle Aurélie, Kongmark Chanapa, Vannier Rose-Noëlle.
    Journal of Solid State Chemistry, vol. 182, pg. 289-294 (2009) DOI
     
  • Electrochemical modification of the catalytic properties of composite membranes of substituted Bi4V2O11 (BIMEVOX) for propane oxidation in a catalytic dense membrane reactor.
    Bodet H., Löfberg A., Pirovano C., Steil M.C., Vannier R.N., Bordes-Richard E.
    Catalysis Today, vol. 141, pg. 260-263 (2009) DOI
     
  • Elucidating the genesis of Bi2MoO6 catalyst by combination of synchrotron radiation experiments and Raman scattering.
    Kongmark Chanapa, Martis Vladimir, Rubbens Annick, Pirovano Caroline, Löfberg Axel, Sankar Gopinathan, Bordes-Richard Elisabeth, Vannier Rose-Noëlle, Van Beek Wouter.
    Chemical Communications, pg. 4850 (2009) DOI
     
  • 2008

  • Structure of Ba2In2−xVxO5+x phases: Complementarity of diffraction, Raman and absorption techniques.
    Rolle A., Daviero-Minaud S., Roussel P., Rubbens A., Vannier R.N.
    Solid State Ionics, vol. 179, pg. 771-775 (2008) DOI
     
  • Characterisation of Ba2In2 − x Sn x O5 + x/2 oxide ion conductors.
    Rolle Aurélie, Seymour Helen, Roussel Pascal, Rubbens Annick, Vannier Rose-Noëlle.
    Ionics, vol. 14, pg. 477-482 (2008) DOI
     
  • Redox stability of Ba2In2O5-doped compounds.
    Rolle A, Fafilek G, Vannier RN.
    Solid State Ionics, vol. 179, pg. 113-119 (2008) DOI
     
  • A neutron diffraction study of the oxygen diffusion in molybdenum doped Ba2In2O5.
    Rolle A, Roussel P, Giridharan N, Suard E, Vannier RN.
    Solid State Ionics, vol. 179, pg. 1986-1995 (2008) DOI
     
  • Raman scattering and X-ray diffraction on YBiTi2O7prepared at low temperature.
    Garbout A., Rubbens A., Vannier R. N., Bouattour S., Kolsi A. W.
    Journal of Raman Spectroscopy, vol. 39, pg. 1469-1474 (2008) DOI
     
  • Polymorphism in PbBiOXO4 compounds (X=V, P, As). Part I: Crystal structures of α- and β-PbBiOVO4.
    Labidi Olfa, Roussel Pascal, Porcher Florence, Drache Michel, Vannier Rose-Noëlle, Wignacourt Jean-Pierre.
    Journal of Solid State Chemistry, vol. 181, pg. 2260-2267 (2008) DOI
     
  • Polymorphism in PbBiOXO4 compounds (X=V, P, As): Part II—PbBiOPO4 and PbBiOAsO4 structures and characterization of related solid solutions.
    Labidi Olfa, Roussel Pascal, Drache Michel, Vannier Rose-Noëlle, Wignacourt Jean-Pierre.
    Journal of Solid State Chemistry, vol. 181, pg. 2268-2273 (2008) DOI
     
  • Variable-Temperature17O NMR Study of Oxygen Motion in the Anionic Conductor Bi26Mo10O69.
    Holmes Lesley, Peng Luming, Heinmaa Ivo, O’Dell Luke A., Smith Mark E., Vannier Rose-Noelle, Grey Clare P.
    Chemistry of Materials, vol. 20, pg. 3638-3648 (2008) DOI
     
  • 2006

  • Oxygen permeation in bismuth-based materials. Part II: Characterisation of oxygen transfer in bismuth erbium oxide and bismuth calcium oxide ceramic.
    CAPOEN E, NOWOGROCKI G, CHATER R, SKINNER S, KILNER J, MALYS M, BOIVIN J, MAIRESSE G, VANNIER R.
    Solid State Ionics, vol. 177, pg. 489-492 (2006) DOI
     
  • Oxygen permeation in bismuth-based materials. Part I: Sintering and oxygen permeation fluxes.
    CAPOEN E, STEIL M, NOWOGROCKI G, MALYS M, PIROVANO C, LOFBERG A, BORDESRICHARD E, BOIVIN J, MAIRESSE G, VANNIER R.
    Solid State Ionics, vol. 177, pg. 483-488 (2006) DOI
     
  • 2005

  • Impedance study of the microstructure dependence of the electrical properties of BIMEVOXes.
    PIROVANO C, STEIL M, CAPOEN E, NOWOGROCKI G, VANNIER R.
    Solid State Ionics, vol. 176, pg. 2079-2083 (2005) DOI
     
  • Thermal stability and preparation of dense membrane ceramics of BIMEVOX.
    STEIL M, RATAJCZAK F, CAPOEN E, PIROVANO C, VANNIER R, MAIRESSE G.
    Solid State Ionics, vol. 176, pg. 2305-2312 (2005) DOI
     
  • Structural and electrochemical characterisation of new oxide ion conductors for oxygen generating systems and fuel cells.
    ROLLE A, VANNIER R, GIRIDHARAN N, ABRAHAM F.
    Solid State Ionics, vol. 176, pg. 2095-2103 (2005) DOI
     
  • 2004

  • Time resolved in-situ neutron diffraction investigation of the electrochemical reduction of BIMEVOX.
    CAPOEN E.
    Solid State Ionics, vol. 175, pg. 419-424 (2004) DOI
     
  • Oxygen permeation versus catalytic properties of bismuth-based oxide ion conductors used for propene oxidation in a catalytic dense membrane reactor.
    Löfberg A, Boujmiai S, Capoen E, Steil M.C, Pirovano C, Vannier R.N, Mairesse G, Bordes-Richard E.
    Catalysis Today, vol. 91-92, pg. 79-83 (2004) DOI
     
  • 2003

  • Characterisation of the electrode–electrolyte BIMEVOX system for oxygen separation Part I. In situ synchrotron study.
    Pirovano C.
    Solid State Ionics, vol. 159, pg. 167-179 (2003) DOI
     

Autres

- Directrice adjointe de l’ENSCL,

- Coordinatrice des Masters à l’ENSCL

- Membre nommé du Conseil Scientifique de l’Institut de Chimie du CNRS,

- Elue Associate Member de la Division II « Chimie Inorganique» de l’IUPAC pour 2012-2013

- Membre actif de l'Association des Anciens Elèves de l'ENSCL,

- Membre de la Société Française de Chimie, Vice-présidente de la section Nord Pas de Calais.

 

-----

Research activities

In charge of the “Solid state group and the "Oxide materials for energy” team at UCCS.

 

Our research activity deals with the characterisation of new oxide ion conductors. As dense ceramics, these materials could be used in Solid Oxide Fuel Cells or Solid Oxide Electrolysis Cell, as membrane for the electrochemical separation of oxygen from air, as sensors, as catalytic membrane reactors. Mixed conductors will be developed as electrode materials. One of our main concerns is the understanding of the mechanism of oxygen transport in these ceramics from the microscopic to the macroscopic scales.

 

X-ray diffraction, Raman scattering, large facilities (neutrons, synchrotron), thermal analyses (TGA, DTA, DSC, dilatometry), impedance spectroscopy, voltametry, isotope exchange combined with SIMS, 17O NMR, are among the techniques we used for the characterisation.

 

We have collaborations with numerous teams. Among these: CEA, EDF, PSA, IMN-Nantes, LECIME ENSC-Paris, LEPMI-Grenoble, IRCE-Lyon, SCR-Rennes, Ecole Centrale de Paris, the department of Materials at Imperial College London, University college London, the University of St-Andrews (UK),  Warsaw University of Technology (Poland), University of Craiova (Roumania), University of Twente (Netherland), University of Shanghai (China), the Universidad Industrial de Santander in Colombia …

 

PhD : "New bi-dimensional oxide ion conductors of Aurivillius type ", 1992, supervised by Professor Gaëtan Mairesse, Laboratoire de Cristallochimie et Physicochimie du Solide, UMR CNRS 8012.

 

HDR : "Oxide ion conductors with low dimensionality - Correlation structure-properties", Lille, 1999.

 

2000-2001 : Marie Curie fellowship at Imperial College London in the group of Professor John Kilner, « Characterisation of oxygen transport phenomena in bismuth based materials by isotope exchange of oxygen ».

 

Teaching activities

Professor at the Ecole Nationale Supérieure de Chimie of Lille

 

As a former student in this school (89), the transfer of my knowledge to student is of great importance. I am in charge of the following courses:

- Inorganic Chemistry (lecture, 1st year),

- Cristallochemistry (lecture, 1st year);

- Techniques of analysis of solids (lecture, 2d year),

- Functional Materials for Energy (lecture, 3d year and master),

- Research project (3d year)

 

Other activities

 

- Second head of the ENSCL

- Coordinator of masters at ENSCL

- Member of the Scientific Council of the Institute of Chemistry at CNRS,

- Elected Associate Member of  Division II « Inorganic Chemistry» at l’IUPAC, 2012-2013

- Member of the ENSCL alumni,

- Member of the French Society of Chemistry, Vice-president of the “Nord Pas-de-Calais” division