Pascal Granger

Full Professor

Catalyse Hétérogène

Bâtiment : C3

Bureau : 012

Téléphone : (+33) 03 20 43 49 38

Fax : (+33) 03 20 43 65 61

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Adresse : Université Lille 1
Cité Scientifique, Bâtiment C3
59650 Villeneuve d'Ascq Cedex
France

Pascal Granger (1964) studied at the University of Poitiers and obtained his Ph.D. degree in applied chemistry in 1992. His thesis was focused on the deactivation of copper based catalysts for biomass conversion in aqueous phase.

After a postdoctoral position at the University of Lille, he obtained a permanent position in 1994 and became full professor in 2003. He managed the surface analysis department of the University of Lille from 2009 to 2012. Now, he is head of the heterogeneous department of the Solid State and Catalysis Laboratory in Lille since 2009.

Research activities

Pascal Granger is currently involved in mechanism and kinetics of heterogeneous catalytic reactions and in the development of in situ and operando spectroscopic characterization especially for reactions involved in post-combustion catalysis and catalytic DeNOx and DeN2O abatement processes. His research interest is also focused on the use of perovskite for the development of low loaded noble metal based catalysts. He is author and co-author of more than 90 publications in peer-reviewed international journals and one book series entitled ‘Past and Present in DeNOx catalysis : From Molecular Modelling to Chemical Engineering’. He obtained two innovative Techniques for the Environment awards from the French Agency for the Sustainable Development (ADEME) in 2000 and in 2001 and the Lecture Prize of the French Chemical Society (Catalysis Division) in 2012.

Research topics

  • DeNOx catalysis from stationary and mobile sources (SCR, NOx storage Reduction systems, NGV catalysis)
  • Reaction kinetic and mechanism
  • In situ and operando spectroscopic techniques
  • Development of perovskite based materials
  • Noble metal catalysts

Teaching activities

Pascal Granger teaches at the University of Lille 1 Sciences and Technologies kinetics and catalysis especially for environmental applications. He is head of the Master Chemistry, Energy and Environment.

Articles récents

Dans la base de données : 64
  • 2016

  • High Intrinsic Catalytic Activity of CeVO4-Based Catalysts for Ammonia-SCR: Influence of pH During Hydrothermal Synthesis.
    Gillot Sylvain, Dacquin Jean-Philippe, Dujardin Christophe, Granger Pascal.
    Topics in Catalysis, vol. 59, pg. 987-995 (2016) DOI
     
  • Catalysis: From academic research to industrial applications.
    Granger Pascal, Agbossou Francine, Ledoux Marc J.
    Comptes Rendus Chimie, vol. 19, pg. 1150-1151 (2016) DOI
     
  • Catalytic Activity and Thermal Stability of LaFe1−xCuxO3 and La2CuO4 Perovskite Solids in Three-Way-Catalysis.
    Schön Anke, Dacquin Jean-Philippe, Dujardin Christophe, Granger Pascal.
    Topics in Catalysis, (2016) DOI
     
  • Reaction Pathways Involved in CH4 Conversion on Pd/Al2O3 Catalysts: TAP as a Powerful Tool for the Elucidation of the Effective Role of the Metal/Support Interface.
    Renème Y., Pietrzyk S., Dhainaut F., Chaar M., van Veen A. C., Granger Pascal.
    Frontiers in Chemistry, vol. 4 (2016) DOI
     
  • Nitrogen-doped carbon nanotube spheres as metal-free catalysts for the partial oxidation of H2S.
    Ba Housseinou, Duong-Viet Cuong, Liu Yuefeng, Nhut Jean-Mario, Granger Pascal, Ledoux Marc J., Pham-Huu Cuong.
    Comptes Rendus Chimie, vol. 19, pg. 1303-1309 (2016) DOI
     
  • Autothermal dry reforming of methane using nickel promoted illite clay catalyst.
    Akri M, Chafik T, Granger P, Ayrault P, Batiot-Dupeyrat C.
    Fuel, vol. 178, pg. 139-147 (2016) DOI
     
  • Hierarchical carbon nanofibers/graphene composite containing nanodiamonds for direct dehydrogenation of ethylbenzene.
    Ba H, Truong-Phuoc L, Liu Y, Duong-Viet C, Nhut J-M, Nguyen-Dinh L, Granger P, Pham-Huu C.
    Carbon, vol. 96, pg. 1060-1069 (2016) DOI
     
  • In situ Raman spectroscopy evidence of an accessible phase potentially involved in the enhanced activity of La-deficient lanthanum orthoferrite in 3-way catalysis (TWC).
    Blanck Dimitri, Schön Anke, Mamede Anne-Sophie, Dujardin Christophe, Dacquin Jean-Philippe, Granger Pascal, Paul Jean-François, Berrier Elise.
    Catalysis Today, (2016) DOI
     
  • 2015

  • Rational preparation of Ag and Au bimetallic catalysts for the hydrocarbon-SCR of NOx: Sequential deposition vs. coprecipitation method.
    More P.M., Nguyen D.L., Dongare M.K., Umbarkar S.B., Nuns N., Girardon J.-S., Dujardin C., Lancelot C., Mamede A.-S., Granger P.
    Applied Catalysis B: Environmental, vol. 162, pg. 11-20 (2015) DOI
     
  • Enhancing catalytic activity of perovskite-based catalysts in three-way catalysis by surface composition optimisation.
    Schön Anke, Dujardin Christophe, Dacquin Jean-Philippe, Granger Pascal.
    Catalysis Today, vol. 258 (2), pg. 543-548 (2015) DOI
     
  • Macroscopic nanodiamonds/β-SiC composite as metal-free catalysts for steam-free dehydrogenation of ethylbenzene to styrene.
    Ba Housseinou, Liu Yuefeng, Mu Xiaoke, Doh Won-Hui, Nhut Jean-Mario, Granger Pascal, Pham-Huu Cuong.
    Applied Catalysis A: General, vol. 499, pg. 217-226 (2015) DOI
     
  • Impact of Deactivation Phenomena on Kinetics of the C–N Coupling Reaction over Supported Cu2O Catalysts in Continuous-Flow Conditions.
    Jurca Bogdan, Tirsoaga Alina, Granger Pascal, Parvulescu Vasile I.
    The Journal of Physical Chemistry C, vol. 119, pg. 18422-18433 (2015) DOI
     
  • A highly N-doped carbon phase “dressing” of macroscopic supports for catalytic applications.
    Ba Housseinou, Liu Yuefeng, Truong-Phuoc Lai, Duong-Viet Cuong, Mu Xiaoke, Doh Won Hui, Tran-Thanh Tung, Baaziz Walid, Nguyen-Dinh Lam, Nhut Jean-Mario, Janowska Izabela, Begin Dominique, Zafeiratos Spiridon, Granger Pascal, Tuci Giulia, Giambastiani Giuliano, Banhart Florian, Ledoux Marc J., Pham-Huu Cuong.
    Chem. Commun., vol. 51, pg. 14393-14396 (2015) DOI
     
  • Activation by pretreatment of Ag–Au/Al2O3 bimetallic catalyst to improve low temperature HC-SCR of NOx for lean burn engine exhaust.
    More Pavan M., Nguyen Duy L., Granger Pascal, Dujardin Christophe, Dongare Mohan K., Umbarkar Shubhangi B.
    Applied Catalysis B: Environmental, vol. 174-175, pg. 145-156 (2015) DOI
     
  • Influence of the reaction temperature on the oxygen reduction reaction on nitrogen-doped carbon nanotube catalysts.
    Truong-Phuoc Lai, Duong-Viet Cuong, Doh Won-Hui, Bonnefont Antoine, Janowska Izabela, Begin Dominique, Savinova Elena R., Granger Pascal, Pham-Huu Cuong.
    Catalysis Today, vol. 249, pg. 236-243 (2015) DOI
     
  • Nanodiamond decorated few-layer graphene composite as an efficient metal-free dehydrogenation catalyst for styrene production.
    Ba Housseinou, Podila Seetharamulu, Liu Yuefeng, Mu Xiaoke, Nhut Jean-Mario, Papaefthimiou Vasiliki, Zafeiratos Spyridon, Granger Pascal, Pham-Huu Cuong.
    Catalysis Today, vol. 249, pg. 167-175 (2015) DOI
     
  • Deoxygenation of oleic acid: Influence of the synthesis route of Pd/mesoporous carbon nanocatalysts onto their activity and selectivity.
    Dragu A., Kinayyigit S., García-Suárez E.J., Florea M., Stepan E., Velea S., Tanase L., Collière V., Philippot K., Granger P., Parvulescu V.I.
    Applied Catalysis A: General, vol. 504, pg. 81-91 (2015) DOI
     
  • Catalytic abatement of NO and N2O from nitric acid plants: A novel approach using noble metal-modified perovskites.
    Wu Y., Dujardin C., Lancelot C., Dacquin J.P., Parvulescu V.I., Cabié M., Henry C.R., Neisius T., Granger P.
    Journal of Catalysis, vol. 328, pg. 236-247 (2015) DOI
     
  • Tunable hierarchical porous silica materials using hydrothermal sedimentation-aggregation technique.
    Zaki Abdelali, Xu Jing, Stoclet Gregory, Casale Sandra, Dacquin Jean-Philippe, Granger Pascal.
    Microporous and Mesoporous Materials, vol. 208, pg. 140-151 (2015) DOI
     
  • 2014

  • Combined IR spectroscopy and kinetic modeling of NOx storage and NO oxidation on Fe-BEA SCR catalysts.
    Skarlis Stavros A., Berthout David, Nicolle André, Dujardin Christophe, Granger Pascal.
    Applied Catalysis B: Environmental, vol. 148-149, pg. 446-465 (2014) DOI
     
  • Combined experimental and kinetic modeling approaches of ammonium nitrate thermal decomposition.
    Skarlis Stavros A., Nicolle André, Berthout David, Dujardin Christophe, Granger Pascal.
    Thermochimica Acta, vol. 584, pg. 58-66 (2014) DOI
     
  • Comparative surface analysis and TAP measurements to probe the NO adsorptive properties of natural gas vehicle Pd–Rh/Al2O3 catalyst.
    Renème Y., Dhainaut F., Schuurman Y., Mirodatos C., Granger P.
    Applied Catalysis B: Environmental, vol. 160-161, pg. 390-399 (2014) DOI
     
  • Supported-induced effect on the catalytic properties of Rh and Pt-Rh particles deposited on La2O3 and mixed α-Al2O3-La2O3 in the dry reforming of methane.
    Ghelamallah Madani, Granger Pascal.
    Applied Catalysis A: General, vol. 485, pg. 172-180 (2014) DOI
     
  • A few-layer graphene–graphene oxide composite containing nanodiamonds as metal-free catalysts.
    Thanh Tung Tran, Ba Housseinou, Truong-Phuoc Lai, Nhut Jean-Mario, Ersen Ovidiu, Begin Dominique, Janowska Izabela, Nguyen Dinh Lam, Granger Pascal, Pham-Huu Cuong.
    Journal of Materials Chemistry A, vol. 2, pg. 11349 (2014) DOI
     
  • An in situ electrical conductivity study of LaCoFe perovskite-based catalysts in correlation with the total oxidation of methane.
    Popescu Ionel, Wu Yihao, Granger Pascal, Marcu Ioan-Cezar.
    Applied Catalysis A: General, vol. 485, pg. 20-27 (2014) DOI
     
  • Evidence of A–B site cooperation in the EuFeO3 perovskite from 151Eu and 57Fe Mössbauer spectroscopy, EXAFS, and toluene catalytic oxidation.
    Florea Mihaela, Alifanti Mihai, Kuncser Victor, Macovei Dan, Apostol Nicoleta, Granger Pascal, Parvulescu Vasile I.
    Journal of Catalysis, vol. 316, pg. 130-140 (2014) DOI
     
  • Steady-state and unsteady-state kinetic approaches for studying reactions over three-way natural gas vehicle catalysts.
    Granger Pascal, Pietrzyk Stan.
    Comptes Rendus Chimie, vol. 17, pg. 656-671 (2014) DOI
     
  • 2013

  • Spectroscopic Investigation of Iron Substitution in EuCoO3: Related Impact on the Catalytic Properties in the High-Temperature N2O Decomposition.
    Wu Y., Dujardin C., Granger P., Tiseanu C., Sandu S., Kuncser V., Parvulescu V.I.
    The Journal of Physical Chemistry C, vol. 117, pg. 13989-13999 (2013) DOI
     
  • Advantages of syngas for the regeneration of NOx trap system investigated with operando IR measurements.
    Dujardin Christophe, Kouakou Anita, Fresnet François, Granger Pascal.
    Catalysis Today, vol. 205, pg. 10-15 (2013) DOI
     
  • Promising Stability of Gold-Based Catalysts Prepared by Direct Anionic Exchange for DeNO x Applications in Lean Burn Conditions.
    Nguyen D.-L., Umbarkar S., Dongare M. K., Lancelot C., Girardon J.-S., Dujardin C., Granger P.
    Topics in Catalysis, vol. 56, pg. 157-164 (2013) DOI
     
  • TAP Investigation of NO Adsorption on Pd/Al2O3: Effect of Thermal Aging.
    Dhainaut F., Renème Y., Pietrzik S., Schuurman Y., Mirodatos C., Granger P.
    Topics in Catalysis, vol. 56, pg. 279-286 (2013) DOI
     
  • Reaction Pathways for Ammonia Formation on Lean NOx Trap/Reduction System: A Spectroscopic Infrared Investigation.
    Dujardin Christophe, Kouakou Anita, Fresnet François, Granger Pascal.
    Topics in Catalysis, vol. 56, pg. 151-156 (2013) DOI
     
  • IR Spectroscopy Analysis and Kinetic Modeling Study for NH3Adsorption and Desorption on H- and Fe-BEA Catalysts.
    Skarlis Stavros A., Berthout David, Nicolle André, Dujardin Christophe, Granger Pascal.
    The Journal of Physical Chemistry C, pg. 130401123828005 (2013) DOI
     
  • Surface reconstructions of LaCo1-xFexO3 at high temperature during N2O decomposition in realistic exhaust gas composition : Impact on the catalytic properties.
    Wu Y, Cordier C, Berrier E, Nuns N, Dujardin C, Granger P.
    Applied Catalysis B: Environmental, vol. 140-141, pg. 151-163 (2013) DOI
     
  • 2012

  • Operando infrared spectroscopy of the reduction of NO by H2 over rhodium based catalysts.
    Carré S., Dujardin C., Granger P.
    Catalysis Today, vol. 191, pg. 59–64 (2012) DOI
     
  • Spectroscopic IR, EPR, and operando DRIFT insights into surface reaction pathways of selective reduction of NO by propene over the Co–BEA zeolite.
    Pietrzyk Piotr, Dujardin Christophe, Góra-Marek Kinga, Granger Pascal, Sojka Zbigniew.
    Physical Chemistry Chemical Physics, vol. 14, pg. 2203 (2012) DOI
     
  • Kinetics of the NO/H2/O2 reactions on natural gas vehicle catalysts—Influence of Rh addition to Pd.
    Renème Y., Dhainaut F., Granger P.
    Applied Catalysis B: Environmental, vol. 111-112, pg. 424-432 (2012) DOI
     
  • Impact of barium and lanthanum incorporation to supported Pt and Rh on α-Al2O3 in the dry reforming of methane.
    Ghelamallah Madani, Granger Pascal.
    Fuel, vol. 97, pg. 269-276 (2012) DOI
     
  • Deposition-precipitation versus anionic-exchange Au/Al2O3 catalysts: A comparative investigation towards the selective reduction of NOx.
    Nguyen D.L., Umbarkar S., Dongare M.K., Lancelot C., Girardon J.-S., Dujardin C., Granger P.
    Catalysis Communications, vol. 26, pg. 225-230 (2012) DOI
     
  • Stoichiometric and non-stoichiometric Perovskite-based catalysts: Consequences on surface properties and on catalytic performances in the decomposition of N2O from nitric acid plants.
    Wu Y., Ni X., Beaurain A., Dujardin C., Granger P.
    Applied Catalysis B: Environmental, vol. 125, pg. 149-157 (2012) DOI
     
  • Multisite Modeling of NH3Adsorption and Desorption over Fe-ZSM5.
    Skarlis Stavros A., Berthout David, Nicolle André, Dujardin Christophe, Granger Pascal.
    The Journal of Physical Chemistry C, vol. 116, pg. 8437-8448 (2012) DOI
     
  • TAP investigation on methane conversion on supported Pd and Rh based catalysts – 1. Kinetics of methane adsorption.
    Renème Y., Dhainaut F., Pietrzyk S., Chaar M., van Veen A.C., Granger P.
    Applied Catalysis B: Environmental, vol. 126, pg. 239-248 (2012) DOI
     
  • 2011

  • Linear Solvation Energy Relationship as a potential predictive tool to investigate catalytic properties: A study of perovskite materials in DeNOx and DeN2O applications.
    Muller S., Dacquin J.P., Wu Y., Dujardin C., Granger P., Burg P.
    Catalysis Today, vol. 176, pg. 433-436 (2011) DOI
     
  • Ceria–zirconia mixed oxides as thermal resistant catalysts for the decomposition of nitrous oxide at high temperature.
    Esteves P., Wu Y., Dujardin C., Dongare M.K., Granger P.
    Catalysis Today, vol. 176, pg. 453-457 (2011) DOI
     
  • Laboratory and pilot scale synthesis, characterization and reactivity of multicomponent cobalt spinel catalyst for low temperature removal of N2O from nitric acid plant tail gases.
    Inger Marek, Kowalik Paweł, Saramok Magdalena, Wilk Marcin, Stelmachowski Paweł, Maniak Gabriela, Granger Pascal, Kotarba Andrzej, Sojka Zbigniew.
    Catalysis Today, vol. 176, pg. 365-368 (2011) DOI
     
  • Catalytic NOxAbatement Systems for Mobile Sources: From Three-Way to Lean Burn after-Treatment Technologies.
    Granger Pascal, Parvulescu Vasile I.
    Chemical Reviews, vol. 111, pg. 3155-3207 (2011) DOI
     
  • Support-Induced Effects of LaFeO3Perovskite on the Catalytic Performances of Supported Pt Catalysts in DeNOxApplications.
    Dacquin J.P., Lancelot C., Dujardin C., Cordier-Robert C., Granger P.
    The Journal of Physical Chemistry C, vol. 115, pg. 1911-1921 (2011) DOI
     
  • 2010

  • NO reduction under diesel exhaust conditions over Au/Al2O3 prepared by deposition-precipitation method.
    Miquel P., Granger P., Jagtap N., Umbarkar S., Dongare M., Dujardin C.
    Journal of Molecular Catalysis A: Chemical, vol. 322, pg. 90-97 (2010) DOI
     
  • Structural changes of nano-Pt particles during thermal ageing: Support-induced effect and related impact on the catalytic performances.
    Dacquin J.P., Cabié M., Henry C.R., Lancelot C., Dujardin C., Raouf S.R., Granger P.
    Journal of Catalysis, vol. 270, pg. 299-309 (2010) DOI
     
  • Pd characterization by XPS in perovskite catalysts for NOx reduction: influence of thermal aging.
    Miquel P., Yamin Y., Lombaert K., Dujardin C., Trentesaux M., Gengembre L., Granger P.
    Surface and Interface Analysis, vol. 42, pg. 545-550 (2010) DOI
     
  • Sol–gel-entrapped nano silver catalysts-correlation between active silver species and catalytic behavior.
    Pârvulescu Vasile I., Cojocaru Bogdan, Pârvulescu Viorica, Richards Ryan, Li Zhi, Cadigan Chris, Granger Pascal, Miquel Pierre, Hardacre Chris.
    Journal of Catalysis, vol. 272, pg. 92-100 (2010) DOI
     
  • XPS investigation of surface changes during thermal aging of Natural Gas Vehicle catalysts: Influence of Rh addition to Pd.
    Renème Y., Dhainaut F., Trentesaux M., Ravanbakhsh B., Granger P., Dujardin C., Gengembre L., De Cola P. L.
    Surface and Interface Analysis, vol. 42, pg. 530-535 (2010) DOI
     
  • 2009

  • Impact of Thermal Aging on the Kinetic Parameters of the NO/H2Reaction on Pd/LaCoO3.
    Dhainaut F., Pietrzyk S., Granger P.
    Langmuir, vol. 25, pg. 13673-13679 (2009) DOI
     
  • Influence of preparation methods of LaCoO3 on the catalytic performances in the decomposition of N2O.
    Dacquin J.P., Lancelot C., Dujardin C., Da Costa P., Djega-Mariadassou G., Beaunier P., Kaliaguine S., Vaudreuil S., Royer S., Granger P.
    Applied Catalysis B: Environmental, vol. 91, pg. 596-604 (2009) DOI
     
  • Thermal Ageing Induced Effects on Pd/LaFeO3 for NOx Reduction by Hydrocarbons: Influence of the Preparation Method.
    Miquel Pierre, Yamin Yas, Lombaert Karine, Dujardin Christophe, Granger Pascal.
    Topics in Catalysis, vol. 52, pg. 1791-1798 (2009) DOI
     
  • Study of Ammonia Formation During the Purge of a Lean NO x Trap.
    Kouakou A., Dhainaut F., Granger P., Fresnet F., Louis-Rose I.
    Topics in Catalysis, vol. 52, pg. 1734-1739 (2009) DOI
     
  • Catalytic Post-Treatment of Automotive Exhaust Gas from Natural Gas Combustion Engines: Potential Interest of Perovskite Materials.
    Renème Y., Dhainaut F., Granger P.
    Topics in Catalysis, vol. 52, pg. 2007-2012 (2009) DOI
     
  • Support modification to improve the sulphur tolerance of Ag/Al2O3 for SCR of NOx with propene under lean-burn conditions.
    Jagtap Neelam, Umbarkar Shubhangi B., Miquel Pierre, Granger Pascal, Dongare Mohan K.
    Applied Catalysis B: Environmental, vol. 90, pg. 416-425 (2009) DOI
     
  • Optimization of Multicomponent Cobalt Spinel Catalyst for N2O Abatement from Nitric Acid Plant Tail Gases: Laboratory and Pilot Plant Studies.
    Stelmachowski Pawel, Zasada Filip, Maniak Gabriela, Granger Pascal, Inger Marek, Wilk Marcin, Kotarba Andrzej, Sojka Zbigniew.
    Catalysis Letters, vol. 130, pg. 637-641 (2009) DOI
     
  • 2008

  • Kinetics of the NO/H2 reaction on Pt/LaCoO3: A combined theoretical and experimental study.
    DHAINAUT F, PIETRZYK S, GRANGER P.
    Journal of Catalysis, vol. 258, pg. 296-305 (2008) DOI
     
  • Catalytic decomposition of N2O on supported Pd catalysts: Support and thermal ageing effects on the catalytic performances.
    Dacquin J.P., Dujardin C., Granger P.
    Catalysis Today, vol. 137, pg. 390-396 (2008) DOI
     
  • WOx-CeO2 and WOx-Nb2O5 catalysts deactivation during hexane isomerization.
    Mamede A.-S., Payen E., Granger P., Florea M., Pârvulescu V. I.
    AIChE Journal, vol. 54, pg. 1303-1312 (2008) DOI
     
  • Surface reconstruction of supported Pd on LaCoO3: Consequences on the catalytic properties in the decomposition of N2O.
    DACQUIN J, DUJARDIN C, GRANGER P.
    Journal of Catalysis, vol. 253, pg. 37-49 (2008) DOI
     
  • An Operando Spectroscopic Investigation of the NO/H2 Reaction on LaCoO3 and Pd-modified LaCoO3  Influence of O2 on Catalyst Performances and Structure of Adsorbed Species.
    Dujardin C., Twagirashema I., Granger P.
    The Journal of Physical Chemistry C, vol. 112, pg. 17183-17192 (2008) DOI