Mathieu Sauthier

Professor

Catalyse et Chimie Moléculaire

 

Bâtiment : C7

Bureau : 905

Téléphone : (+33) 03 20 33 63 01

Fax : (+33) 03 20 43 65 85

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Adresse :

Unité de Catalyse et Chimie du Solide - UMR CNRS 8181
ENSCL, Bâtiment C7
B.P. 90108
Université des Sciences et Technologies de Lille
59652 Villeneuve d’Ascq Cedex
France

Education

2011 Professor at the University of Lille 1 (France) – IUT « A »
Unité de Catalyse et de Chimie du Solide (UCCS)
Homogeneous catalysis – Chemistry of CO and 1,3-butadiene – conversion of bioresources (polyols)
   
2002-2011         Assistant professor at the University of Lille 1 (France) – IUT « A »
HDR (Habilitation – 22th of November 2010)
Unité de Catalyse et de Chimie du Solide (UCCS)
   
2001-2002 Postdoc at the Universiteit van Amsterdam (UVA) in Pr Piet W.N.M. van Leeuwen’s group. Supervision by the Pr. Joost Reek.    
Synthesis of amphiphilic phosphorous based ligands – Hydroformylation under biphasic aqueous phase
   
1998-2001 Ph.D. at the University of Rennes 1 (France)
Director : Pr. R. Réau.
 « New 1,2-diiminophosphoranes and (2-pyridyl)phospholes: New  mixed N,N et P,N ligands for homogeneous catalysis ».
   
1997-1998 Master from the University of Burgundy (Dijon – France).
Director : Pr. R. Guilard.
« Synthesis of porphyrins as biomimetic oxygen carriers »

Current research interest :

Homogeneous catalysis toward organic synthesis
Atom efficiency – greener chemistry – polyols valorization

Chemistry of carbon monoxide

Synthesis of compounds with a carbonyle function

 
(ketoesters, amides, esters, lactones, ketones, diketones ... )

Carbonylative suzuki coupling reactions
Hydroformylation
Alkoxycarbonylation
Hydroesterification
 ...
Catalyst improvements / screening: Catalytic activity (TOF), selectivity and life time (TON).
  Saving synthetic and purification steps

Domino carbonylative reactions: multiple bonds construction under “One pot” conditions.
The construction of elaborated molecules is one step is targeted. Choice of catalysts / reactions conditions and substrates are carefully chosen in order to limit the importance of side reactions or catalyst poisoning.





Example of studied domino reaction:  
   4 new bonds in a “one pot” procedure !

Chemistry of 1,3-butadiene

Clean catalytic etherification reactions with 1,3-butadiene ...

Palladium catalysed telomerization reaction ...  under biphasic conditions: Synthesis of amphiphilic compounds derivred from agro-resources



Nickel catalyzed hydroalkoxylation: Short chain grafting on a hydroxyl function



          ... toward agro-based polyols valorization

 

Book chapters:

BOOK CHAPTER : Carbohydrate Chemistry : Vol. 40 ; 2014 – Royal Society of Chemistry -  Ed. : A. P. Rauter, T. Lindhorst, Y. Queneau
Chapter 5 : “From conventional to greener catalytic approaches for carbohydrates authentification”
M. Sauthier, A. Mortreux, I. Suisse

BOOK CHAPTER : Science of Synthesis: C-1 Building Blocks in Organic Synthesis; Vol. 1; 2014 - Thieme – Ed. P. W. N. M. van Leeuwen
Chapter 1.1.4 : “Nonconventional Reaction Media: Hydroformylation, Carbonylation, and Hydrocarbonylation of Alkenes”
A. Mortreux, M. Sauthier, E. Monflier, S. Tilloy

Bibliographie

Articles

Dans la base de données : 24
  • 2016

  • Nickel(0)-CatalyzedN-Allylation of Amides andp-Toluenesulfonamide with Allylic Alcohols under Neat and Neutral Conditions.
    Azizi Mohamed Salah, Edder Youssef, Karim Abdallah, Sauthier Mathieu.
    European Journal of Organic Chemistry, vol. 2016, pg. 3796-3803 (2016) DOI
     
  • Nickel-Catalysed Bis-Allylation of Activated Nucleophiles with Allyl ­Alcohol.
    Blieck Rémi, Azizi Mohamed Salah, Mifleur Alexis, Roger Maxime, Persyn Clément, Sauthier Mathieu, Bonin Hélène.
    European Journal of Organic Chemistry, vol. 2016, pg. 1194-1198 (2016) DOI
     
  • Telomerization of 1,3-butadiene with glycerol carbonate and subsequent ring-opening lactone co-polymerization.
    Ibn El Alami Mohammed Samir, Suisse Isabelle, Fadlallah Sami, Sauthier Mathieu, Visseaux Marc.
    Comptes Rendus Chimie, vol. 19, pg. 299-305 (2016) DOI
     
  • Synthesis of Short-Chain Alkenyl Ethers from Primary and Bio-sourced Alcohols via the Nickel-Catalyzed Hydroalkoxylation Reaction of Butadiene and Derivatives.
    Mifleur Alexis, Ledru Hélène, Lopes Adrien, Suisse Isabelle, Mortreux André, Sauthier Mathieu.
    Advanced Synthesis < Catalysis, vol. 358, pg. 110-121 (2016) DOI
     
  • 2015

  • Biphasic Palladium-Catalyzed Hydroesterification in a Polyol Phase: Selective Synthesis of Derived Monoesters.
    Pruvost Romain, Boulanger Jérôme, Léger Bastien, Ponchel Anne, Monflier Eric, Ibert Mathias, Mortreux André, Sauthier Mathieu.
    ChemSusChem, vol. 8, pg. 2133-2137 (2015) DOI
     
  • Palladium-catalyzed hydroesterification of olefins with isosorbide in standard and Brønsted acidic ionic liquids.
    Boulanger Jérôme, Seingeot Adeline, Léger Bastien, Pruvost Romain, Ibert Mathias, Mortreux André, Chenal Thomas, Sauthier Mathieu, Ponchel Anne, Monflier Eric.
    Catalysis Communications, vol. 69, pg. 143-146 (2015) DOI
     
  • 2014

  • Synthesis of 1,4:3,6-Dianhydrohexitols Diesters from the Palladium-Catalyzed Hydroesterification Reaction.
    Pruvost Romain, Boulanger Jérôme, Léger Bastien, Ponchel Anne, Monflier Eric, Ibert Mathias, Mortreux André, Chenal Thomas, Sauthier Mathieu.
    ChemSusChem, vol. 7 (11), pg. 3157-3163 (2014) DOI
     
  • Transition Metal-Mediated Direct CH Arylation of Heteroarenes Involving Aryl Radicals.
    Bonin Hélène, Sauthier Mathieu, Felpin François-Xavier.
    Advanced Synthesis < Catalysis, vol. 356, pg. 645-671 (2014) DOI
     
  • 2013

  • Synthesis of α-Alkylated β-Ketoesters by Alkoxycarbonylation/Michael Addition Domino Reaction.
    Wahl Benoit, Philipson Yann, Bonin Hélène, Mortreux André, Sauthier Mathieu.
    The Journal of Organic Chemistry, vol. 78, pg. 1547-1552 (2013) DOI
     
  • Nickel-Catalysed Hydroalkoxylation Reaction of 1,3-Butadiene: Ligand Controlled Selectivity for the Efficient and Atom-Economical Synthesis of Alkylbutenyl Ethers.
    Bigot Sandra, El Alami Mohammed Samir Ibn, Mifleur Alexis, Castanet Yves, Suisse Isabelle, Mortreux André, Sauthier Mathieu.
    Chemistry - A European Journal, vol. 19, pg. 9785-9788 (2013) DOI
     
  • 2012

  • Straightforward Synthesis of Allylated Keto Esters: The Palladium-Catalysed Haloketone Alkoxycarbonylation/ Allylation Domino Reaction.
    Wahl Benoit, Giboulot Steven, Mortreux André, Castanet Yves, Sauthier Mathieu, Liron Frédéric, Poli Giovanni.
    Advanced Synthesis < Catalysis, vol. 354, pg. 1077-1083 (2012) DOI
     
  • Pd-catalyzed domino carbonylative–decarboxylative allylation: an easy and selective monoallylation of ketones.
    Giboulot Steven, Liron Frédéric, Prestat Guillaume, Wahl Benoit, Sauthier Mathieu, Castanet Yves, Mortreux André, Poli Giovanni.
    Chemical Communications, vol. 48, pg. 5889 (2012) DOI
     
  • Effect of Chain Unsaturation on the Self-Association of Tri- and Tetraethylene Glycol Octyl Ethers Obtained by Butadiene Telomerization.
    Lai Jonathan, Molinier Valérie, Sauthier Mathieu, Moity Laurianne, Castanet Yves, Mortreux André, Aubry Jean-Marie.
    Langmuir, vol. 28, pg. 242-250 (2012) DOI
     
  • A General and Efficient Method for the Alkoxycarbonylation of α-Chloro Ketones.
    Wahl Benoit, Bonin Hélène, Mortreux André, Giboulot Steven, Liron Frédéric, Poli Giovanni, Sauthier Mathieu.
    Advanced Synthesis < Catalysis, vol. 354, pg. 3105-3114 (2012) DOI
     
  • 2011

  • Telomerisation of 1,3-Butadiene with 1,4:3,6-Dianhydrohexitols: An Atom-Economic and Selective Synthesis of Amphiphilic Monoethers from Agro-Based Diols.
    Lai Jonathan, Bigot Sandra, Sauthier Mathieu, Molinier Valérie, Suisse Isabelle, Castanet Yves, Aubry Jean-Marie, Mortreux André.
    ChemSusChem, vol. 4, pg. 1104-1111 (2011) DOI
     
  • 2010

  • Organometallic catalysis: From concepts to selected applications.
    Sauthier Mathieu, Zinck Philippe, Mortreux André.
    Comptes Rendus Chimie, vol. 13, pg. 304-314 (2010) DOI
     
  • Telomerisation of 1,3-butadiene with glycerol under aqueous biphasic conditions: Influence of the reaction conditions on the products distribution.
    Bigot Sandra, Lai Jonathan, Suisse Isabelle, Sauthier Mathieu, Mortreux André, Castanet Yves.
    Applied Catalysis A: General, vol. 382, pg. 181-189 (2010) DOI
     
  • New Synthesis of Furans: the Rhodium-Catalysed Carbonylative Addition of Arylboronic Acids to Propargylic Alcohols/ Cyclisation Sequence.
    Dheur Julien, Sauthier Mathieu, Castanet Yves, Mortreux André.
    Advanced Synthesis < Catalysis, vol. 352, pg. 557-561 (2010) DOI
     
  • 2009

  • Palladium-Catalysed Carbonylative Cross-Coupling Reactions of Aryl Iodides and Vinyl Boron Derivatives as a Straightforward Route to Aryl Vinyl Ketones.
    Castanet Yves, Sauthier Mathieu, Pirez Cyril, Dheur Julien, Mortreux André.
    Synlett, vol. 2009, pg. 1745-1748 (2009) DOI
     
  • Carbonylative 1,4-addition of potassium aryltrifluoroborates to vinyl ketones.
    Sauthier Mathieu, Lamotte Nicolas, Dheur Julien, Castanet Yves, Mortreux André.
    New Journal of Chemistry, vol. 33, pg. 969 (2009) DOI
     
  • Aqueous hydroformylation reaction mediated by randomly methylated β-cyclodextrin: How substitution degree influences catalytic activity and selectivity.
    Legrand François-Xavier, Sauthier Mathieu, Flahaut Christophe, Hachani Johan, Elfakir Claire, Fourmentin Sophie, Tilloy Sébastien, Monflier Eric.
    Journal of Molecular Catalysis A: Chemical, vol. 303, pg. 72-77 (2009) DOI
     
  • 2008

  • 1,4-Conjugate addition reaction catalyzed by a homogeneous rhodium catalyst entrapped in hydrophobized ordered mesoporous silica.
    Handa Paul, Holmberg Krister, Sauthier Mathieu, Castanet Yves, Mortreux André.
    Microporous and Mesoporous Materials, vol. 116, pg. 424-431 (2008) DOI
     
  • 2005

  • Rhodium Complexes Non-Covalently Bound to Cyclodextrins: Novel Water-Soluble Supramolecular Catalysts for the Biphasic Hydroformylation of Higher Olefins.
    Sueur Benoît, Leclercq Loïc, Sauthier Mathieu, Castanet Yves, Mortreux André, Bricout Hervé, Tilloy Sébastien, Monflier Eric.
    Chemistry - A European Journal, vol. 11, pg. 6228-6236 (2005) DOI
     
  • Two-Phase Hydroformylation of Higher Olefins Using Randomly Methylated ?-Cyclodextrin as Mass Transfer Promoter: A Smart Solution for Preserving the Intrinsic Properties of the Rhodium/Trisulfonated Triphenylphosphine Catalytic System.
    Leclercq Loïc, Sauthier Mathieu, Castanet Yves, Mortreux André, Bricout Hervé, Monflier Eric.
    Advanced Synthesis < Catalysis, vol. 347, pg. 55-59 (2005) DOI