Francine Agbossou

Directeur de recherches CNRS

Catalyse et Chimie Moléculaire

 

Bâtiment : C7

Bureau : 108

Téléphone : (+33) 03 20 43 49 27

Fax : (+33) 03 20 43 65 85

Email : Cette adresse e-mail est protégée contre les robots spammeurs. Vous devez activer le JavaScript pour la visualiser.">francine.agbossou@ensc-lille.fr

Adresse :

Unité de Catalyse et Chimie du Solide - UMR CNRS 8181
ENSCL, Bâtiment C7
B.P. 90108
Université des Sciences et Technologies de Lille
59652 Villeneuve d’Ascq Cedex
France

Thèmes de recherche

  • Design d’auxiliaires chiraux et applications en catalyse asymétrique,
  • Liquids ioniques, milieux organisés et catalyse
  • Synthèse asymétrique
  • Catalyse énantiosélective d’hydrogenation, hydroformylation, allylation, silylcyanation et formations de liaisons C-C, hydroamination
  • carbones quaternaires chiraux
  • réactions multicomposants

Parcours de recherche

1978-1980 : thèse 3ème cycle

Métalloporphyrines Université Nancy 1 Dir. thèse : Pr. Bertrand Castro

1981-1985 : thèse Doctorat d’Etat

Attachée de Recherche CNRS Modèles de cytochrome P 450 Institut de Recherche sur la Catalyse, Villeurbanne Dir.thèse : Dr Igor Tkatchenko

1985-1988

Chargée de Recherche Catalyse homogène Laboratoire de Chimie de Coordination Toulouse Dir. : Dr Igor Tkatchenko

1988-1989

Stage Post doctoral Complexes chiraux du rhénium Université d’Utah, Salt Lake City, USA Dir. : Pr John Gladysz

1990-présent

Laboratoire de Catalyse de Lille Unité de Catalyse et de Chimie du Solide

Bibliographie récente

Ouvrages

Aminophosphine-Phosphinites, F. Agbossou-Niedercorn, in Phosphorous Ligands in Asymmetric Catalysis. Synthesis and Applications, Börner, A. (ed.) Wiley-VCH (2008) pp 477-505.

Articles

  Dans la base de données : 47

  • 2017

  • Total Synthesis of (–)-Herbaric Acid through Organocatalyzed Asymmetric Halolactonization of Acrylate-Type Benzoic Acids.
    Deniau Eric, Michon Christophe, Gelat Fabien, Lebrun Stéphane, Henry Natacha, Agbossou-Niedercorn Francine.
    Synlett, vol. 28, pg. 225-230 (2017) DOI
     
  • 2016

  • First catalytic asymmetric hydrogenation of quinoxaline-2-carboxylates.
    Maj Anna M., Heyte Svetlana, Araque Marcia, Dumeignil Franck, Paul Sébastien, Suisse Isabelle, Agbossou-Niedercorn Francine.
    Tetrahedron, vol. 72, pg. 1375-1380 (2016) DOI
     
  • Asymmetric hydrogenation of 2,3-dihydro-1H-inden-1-one oxime and derivatives.
    Maj Anna M., Suisse Isabelle, Agbossou-Niedercorn Francine.
    Tetrahedron: Asymmetry, vol. 27, pg. 268-273 (2016) DOI
     
  • Pentamethylcyclopentadienyl Iridium(III) Metallacycles Applied to Homogeneous Catalysis for Fine Chemical Synthesis.
    Michon Christophe, MacIntyre Kirsty, Corre Yann, Agbossou-Niedercorn Francine.
    ChemCatChem, vol. 8, pg. 1755-1762 (2016) DOI
     
  • Regioselective hydrosilylation of terminal alkynes using pentamethylcyclopentadienyl iridium(III) metallacycle catalysts.
    Corre Yann, Werlé Christophe, Brelot-Karmazin Lydia, Djukic Jean-Pierre, Agbossou-Niedercorn Francine, Michon Christophe.
    Journal of Molecular Catalysis A: Chemical, vol. 423, pg. 256-263 (2016) DOI
     
  • Regioselective organocatalyzed asymmetric bromolactonization of aryl acrylate-type carboxylic acids: a new approach towards enantioenriched 3-substituted isobenzofuranones.
    Gelat Fabien, Coffinet Michaël, Lebrun Stéphane, Agbossou-Niedercorn Francine, Michon Christophe, Deniau Eric.
    Tetrahedron: Asymmetry, vol. 27, pg. 980-989 (2016) DOI
     
  • Selective Hydrosilylation of Esters to Aldehydes Catalysed by Iridium(III) Metallacycles through Trapping of Transient Silyl Cations.
    Corre Yann, Rysak Vincent, Capet Frédéric, Djukic Jean-Pierre, Agbossou-Niedercorn Francine, Michon Christophe.
    Chemistry - A European Journal, vol. 22, pg. 14036-14041 (2016) DOI
     
  • Synthesis of symmetrical diaryl ketones by cobalt-catalysed reaction of arylzinc reagents with ethyl chloroformate.
    Rérat A, Michon C, Agbossou-Niedercorn F, Gosmini C.
    Eur. J. Org. Chem., vol. 2016, pg. 4554-4560 (2016) DOI
     
  • 2015

  • Efficient hydrosilylation of imines using catalysts based on iridium(iii) metallacycles.
    Corre Y., Iali W., Hamdaoui M., Trivelli X., Djukic J.-P., Agbossou-Niedercorn F., Michon C.
    Catal. Sci. Technol., (2015) DOI
     
  • Chiral Ligands Derived from Monoterpenes: Application in the Synthesis of Optically Pure Secondary Alcohols via Asymmetric Catalysis.
    El Alami Mohammed Samir Ibn, El Amrani Mohamed Amin, Agbossou-Niedercorn Francine, Suisse Isabelle, Mortreux André.
    Chemistry - A European Journal, vol. 21, pg. 1398-1413 (2015) DOI
     
  • Chiral Phase-Transfer-Catalyzed Intramolecular aza-Michael Reactions for the Asymmetric Synthesis of Isoindolinones.
    Lebrun Stéphane, Sallio Romain, Dubois Mélanie, Agbossou-Niedercorn Francine, Deniau Eric, Michon Christophe.
    European Journal of Organic Chemistry, vol. 2015, pg. 1995-2004 (2015) DOI
     
  • 2014

  • Highly enantioselective synthesis of terutroban key intermediate via asymmetric hydrogenation.
    Maj Anna M., Suisse Isabelle, Pinault Nathalie, Agbossou-Niedercorn Francine.
    Comptes Rendus Chimie, vol. 17, pg. 725-730 (2014) DOI
     
  • Chiral phenoxyimino-amido aluminum complexes for the asymmetric cyanation of aldehydes.
    Ternel J., Agbossou-Niedercorn F., Gauvin R. M.
    Dalton Transactions, vol. 43, pg. 4530 (2014) DOI
     
  • Mononuclear gold catalysts for the asymmetric intramolecular hydroamination of alkenes.
    Michon Christophe, Abadie Marc-Antoine, Medina Florian, Agbossou-Niedercorn Francine.
    Catalysis Today, vol. 235, pg. 2-13 (2014) DOI
     
  • Asymmetric Intramolecular Hydroamination of Alkenes in Mild and Wet Conditions-Structure and Reactivity of Cationic Binuclear Gold(I) Catalysts.
    Abadie Marc-Antoine, Trivelli Xavier, Medina Florian, Capet Frédéric, Roussel Pascal, Agbossou-Niedercorn Francine, Michon Christophe.
    ChemCatChem, vol. 6, pg. 2235-2239 (2014) DOI
     
  • Molybdenum(VI) dioxo complexes for the epoxidation of allylic alcohols and olefins.
    Pandhare Swati L., Jadhao Rajesh R., Puranik Vedavati G., Joshi Pranaya V., Capet Frédéric, Dongare Mohan K., Umbarkar Shubhangi B., Michon Christophe, Agbossou-Niedercorn Francine.
    Journal of Organometallic Chemistry, vol. 772-773, pg. 271-279 (2014) DOI
     
  • Efficient Catalytic Hydrogenation of N-Unsubstituted Cyclic Imides to Cyclic Amines.
    Maj Anna M., Suisse Isabelle, Pinault Nathalie, Robert Nicolas, Agbossou-Niedercorn Francine.
    ChemCatChem, vol. 6, pg. 2621-2625 (2014) DOI
     
  • Efficient gold(I) catalysed asymmetric hydroamination of alkenes.
    Abadie M -A, Medina F, Agbossou-Niedercorn F, Michon C.
    Chimica OGGI – Chemistry Today , vol. 32 (6), pg. 19-21 (2014)
     
  • 2013

  • Catalytic Asymmetric Allylic Alkylation of 3-Arylated Piperidin-2-ones.
    Michon Christophe, Béthegnies Aurélien, Capet Frédéric, Roussel Pascal, de Filippis Arnault, Gomez-Pardo Domingo, Cossy Janine, Agbossou-Niedercorn Francine.
    European Journal of Organic Chemistry, vol. 22, pg. 4979-4985 (2013) DOI
     
  • Enantioenriched Isoindolinones from Chiral Phase-Transfer-Catalyzed Intramolecular Aza-Michael Reactions.
    Michon Christophe, Deniau Eric, Sallio Romain, Lebrun Stéphane, Schifano-Faux Nadège, Goossens Jean-François, Agbossou-Niedercorn Francine.
    Synlett, vol. 24, pg. 1785-1790 (2013) DOI
     
  • Dismantling the salen framework: design of new asymmetric silylcyanation catalysts.
    Ternel Jérémy, Roussel Pascal, Agbossou-Niedercorn Francine, Gauvin Régis M.
    Catalysis Science < Technology, (2013) DOI
     
  • Uncatalysed intermolecular aza-Michael reactions.
    Medina Florian, Duhal Nathalie, Michon Christophe, Agbossou-Niedercorn Francine.
    Comptes Rendus Chimie, vol. 16, pg. 311-317 (2013) DOI
     
  • Preparation of chiral key intermediates of morpholine based neurokinin receptor antagonists by asymmetric allylic alkylation.
    Keldenich Jérôme, Denicourt-Nowicki Audrey, Michon Christophe, Agbossou-Niedercorn Francine.
    Tetrahedron, vol. 69, pg. 6424-6430 (2013) DOI
     
  • Asymmetric Intramolecular Hydroamination of Allenes using Mononuclear Gold Catalysts.
    Michon Christophe, Medina Florian, Abadie Marc-Antoine, Agbossou-Niedercorn Francine.
    Organometallics, vol. 32, pg. 5589-5600 (2013) DOI
     
  • Synthesis of new chiral 2-functionalized-1,2,3,4-tetrahydroquinoline derivatives via asymmetric hydrogenation of substituted quinolines.
    Maj Anna M., Suisse Isabelle, Hardouin Christophe, Agbossou-Niedercorn Francine.
    Tetrahedron, vol. 69, pg. 9322-9328 (2013) DOI
     
  • 2012

  • Inclusion of tetrabutylammonium cations in a chiral thiazolium/triflate network: Solid state and solution structural investigation.
    Leclercq Loïc, Suisse Isabelle, Roussel Pascal, Agbossou-Niedercorn Francine.
    Journal of Molecular Structure, vol. 1010, pg. 152-157 (2012) DOI
     
  • Fast and efficient solvent-free Passerini reaction.
    Bousquet Till, Jida Mouhamad, Soueidan Mohamad, Deprez-Poulain Rebecca, Agbossou-Niedercorn Francine, Pelinski Lydie.
    Tetrahedron Letters, vol. 53, pg. 306-308 (2012) DOI
     
  • Alternative strategies for the stereoselective synthesis of enantioenriched 6-arylated piperidin-2-ones.
    Sallio Romain, Lebrun Stéphane, Agbossou-Niedercorn Francine, Michon Christophe, Deniau Eric.
    Tetrahedron: Asymmetry, vol. 23, pg. 998-1004 (2012) DOI
     
  • Intermolecular Mono- and Dihydroamination of Activated Alkenes Using a Recoverable Gold Catalyst.
    Medina Florian, Michon Christophe, Agbossou-Niedercorn Francine.
    European Journal of Organic Chemistry, vol. 2012, pg. 6218-6227 (2012) DOI
     
  • Stereoselective synthesis of enantiopure N-protected-3-arylpiperazines from keto-esters.
    Jida Mouhamad, Laconde Guillaume, Soueidan Olivier-Mohamad, Lebegue Nicolas, Revelant Germain, Pelinski Lydie, Agbossou-Niedercorn Francine, Deprez Benoit, Deprez-Poulain Rebecca.
    Tetrahedron Letters, vol. 53, pg. 5215-5218 (2012) DOI
     
  • Highly enantioselective hydrogenation of new 2-functionalized quinoline derivatives.
    Maj Anna M., Suisse Isabelle, Méliet Catherine, Hardouin Christophe, Agbossou-Niedercorn Francine.
    Tetrahedron Letters, vol. 53, pg. 4747-4750 (2012) DOI
     
  • 2011

  • A facile and rapid synthesis of N-benzyl-2-substituted piperazines.
    Jida Mouhamad, Soueidan Mohamad, Willand Nicolas, Agbossou-Niedercorn Francine, Pelinski Lydie, Laconde Guillaume, Deprez-Poulain Rebecca, Deprez Benoit.
    Tetrahedron Letters, vol. 52, pg. 1705-1708 (2011) DOI
     
  • Synthesis and Application in Catalysis of Planar Chiral (η5-Cyclohexadienyl)tricarbonylmanganese-Based Ligands.
    Rose-Munch Françoise, Cetiner Derya, Chavarot-Kerlidou Murielle, Rose Eric, Agbossou-Niedercorn Francine, Chamoreau Lise-Marie, Gontard Geoffrey.
    Organometallics, vol. 30, pg. 3530-3543 (2011) DOI
     
  • Synthesis of a Chiral Key Intermediate of Neurokinin Antagonist SSR 240600 by Asymmetric Allylic Alkylation.
    Agbossou-Niedercorn Francine, Keldenich Jérôme, Michon Christophe, Nowicki Audrey.
    Synlett, vol. 2011, pg. 2939-2942 (2011) DOI
     
  • 2010

  • Design of a well-defined, silica-supported chiral Zn scaffold for enantioselective catalysis.
    Ternel Jérémy, Delevoye Laurent, Agbossou-Niedercorn Francine, Roisnel Thierry, Gauvin Régis M., Thomas Christophe M.
    Dalton Transactions, vol. 39, pg. 3802 (2010) DOI
     
  • Solvent-free microwave-assisted Meyers’ lactamization.
    Jida Mouhamad, Deprez-Poulain Rebecca, Malaquin Sandra, Roussel Pascal, Agbossou-Niedercorn Francine, Deprez Benoit, Laconde Guillaume.
    Green Chemistry, vol. 12, pg. 961 (2010) DOI
     
  • Kinetic Resolution of Racemic Secondary Alcohols Mediated by N-Methylimidazole in the Presence of Optically Active Acyl Chlorides.
    Leclercq Loïc, Suisse Isabelle, Agbossou-Niedercorn Francine.
    European Journal of Organic Chemistry, vol. 2010, pg. 2696-2700 (2010) DOI
     
  • Enantioselective hydrogenation of indoles derivatives catalyzed by Walphos/rhodium complexes.
    Maj Anna M., Suisse Isabelle, Méliet Catherine, Agbossou-Niedercorn Francine.
    Tetrahedron: Asymmetry, vol. 21, pg. 2010-2014 (2010) DOI
     
  • Inter- and Intramolecular Hydroamination of Unactivated Alkenes Catalysed by a Combination of Copper and Silver Salts: The Unveiling of a Brønstedt Acid Catalysis.
    Michon Christophe, Medina Florian, Capet Frédéric, Roussel Pascal, Agbossou-Niedercorn Francine.
    Advanced Synthesis < Catalysis, vol. 352, pg. 3293-3305 (2010) DOI
     
  • 2009

  • Synthesis of chiral bifunctional ligands based on α-pinene and their use in ruthenium catalyzed asymmetric transfer hydrogenation.
    Elalami Mohammed Samir Ibn, Dahdouh Abdel Aziz, Mansour Ahmed Ibn, ElAmrani Mohammed Amin, Suisse Isabelle, Mortreux André, Agbossou-Niedercorn Francine.
    Comptes Rendus Chimie, vol. 12, pg. 1253-1258 (2009) DOI
     
  • 1,1′-Binaphthyl-2-methylpyridinium-Based Peroxophosphotungstate Salts: Synthesis, Characterization, and Their Use as Oxidation Catalysts.
    Jahier Claire, Felpin François-Xavier, Agbossou-Niedercorn Francine, Hierso Jean-Cyrille, Nlate Sylvain, Meliet Catherine.
    European Journal of Inorganic Chemistry, vol. 2009, pg. 5148-5155 (2009) DOI
     
  • Enantiopure Dendritic Polyoxometalates: Chirality Transfer from Dendritic Wedges to a POM Cluster for Asymmetric Sulfide Oxidation.
    Jahier Claire, Cantuel Martine, McClenaghan Nathan D., Buffeteau Thierry, Cavagnat Dominique, Agbossou Francine, Carraro Mauro, Bonchio Marcella, Nlate Sylvain.
    Chemistry - A European Journal, vol. 15, pg. 8703-8708 (2009) DOI
     
  • 2008

  • On the solid state inclusion of tetrabutylammonium cation in the imidazolium/trifluoromethanesulfonate H-bonds network observed in ionic co-crystals.
    Leclercq Loïc, Suisse Isabelle, Nowogrocki Guy, Agbossou-Niedercorn Francine.
    Journal of Molecular Structure, vol. 892, pg. 433-437 (2008) DOI
     
  • Desymmetrization ofmeso-Bicyclic Hydrazines by Rhodium-Catalyzed Enantioselective Hydroformylation.
    Bournaud Chloée, Lecourt Thomas, Micouin Laurent, Méliet Catherine, Agbossou-Niedercorn Francine.
    European Journal of Organic Chemistry, vol. 2008, pg. 2298-2302 (2008) DOI
     
  • Biphasic hydroformylation in ionic liquids: interaction between phosphane ligands and imidazolium triflate, toward an asymmetric process.
    Leclercq Loïc, Suisse Isabelle, Agbossou-Niedercorn Francine.
    Chemical Communications, pg. 311 (2008) DOI
     
  • Preparation of pyridinyl aryl methanol derivatives by enantioselective hydrogenation of ketones using chiral Ru(diphosphine)(diamine) complexes. Attribution of their absolute configuration by 1H NMR spectroscopy using Mosher<#039;s reagent.
    Maerten Eddy, Agbossou-Niedercorn Francine, Castanet Yves, Mortreux André.
    Tetrahedron, vol. 64, pg. 8700-8708 (2008) DOI
     
  • 2007

  • Halide-free highly-pure imidazolium triflate ionic liquids: Preparation and use in palladium-catalysed allylic alkylation.
    Leclercq Loïc, Suisse Isabelle, Nowogrocki Guy, Agbossou-Niedercorn Francine.
    Green Chemistry, vol. 9, pg. 1097 (2007) DOI
     

 

2008-2005

  • Desymmetrization of meso-bicyclic hydrazines by rhodium catalyzed enantioselective hydroformylation. C. Bournaud, T. Lecourt, L. Micouin, C. Méliet, F. Agbossou-Niedercorn, Eur. J. Org. Chem. (2008) 2298-2302. doi.wiley.com/10.1002/ejoc.200800116
  • Biphasic hydroformylation in ionic liquids : interaction between phosphane ligands and imidazolium triflate, toward an asymmetric process. L. Leclercq, I. Suisse, F. Agbossou-Niedercorn, Chem. Commun. (2008) 311-313 DOI : 10.1039/b716015a
  • Halide-free highly-pure imidazolium triflate ionic liquids : Preparation and use in palladium-catalysed allylic alkylation. L. Leclercq, I. Suisse, G. Nowogrocki, F. Agbossou-Niedercorn, Green Chem. 9 (2007) 1097-1103. DOI : 10.1039/b703096g
  • Highly Selective Preparation of a Chiral Quaternary Allyl Aryl Piperidinedione by Palladium-Catalyzed Asymmetric Allylation Under Solid–Liquid Phase-Transfer Catalysis. A. Nowicki, J. Keldenich, F. Agbossou-Niedercorn, Eur. J. Org. Chem. (2007) 6124-6127.
  • Tetrathiafulvalene-oxazoline ligands in the iridium-catalyzed enantioselective hydrogenation of arylimines. C. Réthoré, F. Riobé, M. Fourmigué, N. Avarvari, I. Suisse, F. Agbossou-Niedercorn, Tetrahedron : Asymmetry 18 (2007) 1877-1882. doi:10.1016/j.tetasy.2007.07.019
  • A density functional study of the hydrogenation of ketones catalysed by neutral rhodium-diphosphane complexes. F. Agbossou-Niedercorn, J.F. Paul, Eur. J. Inorg. (2006) 4338-4348.
  • Chiral tetrathiafulvalene based phosphine- and thiomethyl-oxazoline ligands. Evaluation in palladium catalysed asymmetric allylic alkylation. C. Réthoré, I. Suisse, F. Agbossou-Niedercorn, E. Guillamon, R. Llusar, M. Fourmigué, N. Avarvari, Tetrahedron 62 (2006) 11942-11947.doi : 10.1016/j.tetasy.2007.07.019
  • Construction of quaternary carbon stereocentres : catalytic enantioselective allylation assisted by a bimetallic catalytic system. A. Nowicki, A. Mortreux, F. Agbossou-Niedercorn, Tetrahedron : Asymmetry 16 (2005), 1295-1298. doi : 10.1016/j.tetasy.2005.02.009
  • Catalytic enantioselective allylation at the activated benzylic position of prochiral cyano esters : access to quaternary stereogenic centers. A. Nowicki, A. Mortreux, F. Agbossou-Niedercorn, Tetrahedron Lett. 46 (2005) 1617-1621. doi : 10.1016/j.tetlet.2005.01.082