Equipe CÏSCO - CÏSCO team

Colloïdes catalyse oxydation

Colloids catalysis oxidation

Mots-clefs - Key words

Oxydation, Catalyse interfaciale, Formulation, Détergence, Cosmétique, Parfums, Systèmes dispersés, Emulsion, Microémulsion, Tensioactif, Hydrotrope, Antioxydant, Solvant vert, Modélisation, COSMO-RS, Paramètres de solubilité

Oxidation, Interfacial catalysis, Formulation, Detergency, Cosmetic, Fragrances, Dispersed systems, Emulsion, Microemulsion, Surfactant, Hydrotrope, Antioxidant, Green solvent, Modeling, COSMO-RS, Solubility parameters

 

 MEMBRES DE L'EQUIPE - TEAM MEMBERS
Nom Fonction Institution Web
Rataj V. Professeur Univ. Lille  
Aubry J.-M. Professeur
Univ. Lille page
Catte M. Maître de Conférences Univ. Lille page
Dechezelles J.-F. Chargée de Recherche ENSCL page
Lebeuf R.
Maître de Conférences Univ. Lille page
Leclercq L.
Maître de Conférences Univ. Lille page
Ontiveros F. Maître de Conférences ENSCL page
Ortega M. Assistant Ingénieur
Univ. Lille page
Pierlot C. Maître de Conférences ENSCL page

 

  MOT DU RESPONSABLE D’ÉQUIPE       TEAM LEADER FOREWORD  
 

La volonté, en 1989, de développer une recherche spécifique en chimie de formulation à Lille a conduit à réunir dans une même entité des compétences variées (oxydation, catalyse, physicochimie colloïdale, modélisation moléculaire,
chimiométrie). Initialement associée au LCOM (Laboratoire de Chimie Organique et Macromoléculaire, UMR 8009), l’équipe a intégré l’UCCS en janvier 2015 et est devenue l’équipe CïSCO. Ses activités de recherche intègrent 3 domaines de compétences : l’oxydation, les composés fonctionnels agro-sourcés et la chimie de formulation. Grâce aux synergies découlant de ses expertises, l’équipe bénéficie d’une notoriété nationale et internationale, générant de nombreuses collaborations académiques et industrielles. Elle participe activement aux programmes de recherche régionaux (CPER, Chimie et Matériaux), nationaux (ANR, FUI) ou internationaux (PCP France-Venezuela, projet Sakura France-Japon, projet européen). Elle est également fortement impliquée dans les projets des ITE IFMAS et PIVERT.

Véronique Rataj, Professeur à Univ. Lille

     

The wish, in 1989, to develop a specific research in Formulation chemistry led to bring together various skills (oxidation, catalysis, colloidal physicochemistry, molecular modeling, chemometry) in a same entity. Initially part of the LCOM (Laboratoire de Chimie Organique et Macromoléculaire, UMR 8009), the team has integrated the UCCS in January 2015 becoming the CISCO team. Its area of expertise includes oxidation, agro-sourced functional compounds and physicochemistry of formulation. Thanks to the synergies stemming from its expertise, the CISCO team has a national and international recognition, with numerous academic and industrial collaborative partnerships. It participates actively in the regional (CPER, Chemistry and Materials), national (ANR, ADEME, FUI) or international (PCP France-Venezuela, Sakura France-Japan project, European project) research programs. It is also very active in the projects of the IFMAS and PIVERT ITEs.

Véronique Rataj, Professor at Univ. Lille

 
             
  CHIFFRES CLES       KEY FIGURES  
 

8 enseignants-chercheurs et 1 assistant ingénieur
77 publications (IFmoy = 4,3), 8 chapitres de livre
18 doctorants, 7 CDDs ingénieurs et 2 post-doctorants
1 projet européen, 2 contrats ANR, 3 programmes ITE IFMAS et 3 programmes ITE PIVERT
8 contrats industriels d’une durée de 1 à 3 ans
9 brevets déposés

     

8 teacher-researchers - 1 assistant engineer
77 publications (IFmean = 4.3), 8 book chapters
18 PhDs, 7 CDDs, 2 post-doctorants
1 European project, 2 ANR projects, 6 projects with the ITEs IFMAS and PIVERT
8 industrial collaborations from 1 to 3 years (CDD or PhD)
9 patents

 

 

Téléchargez la fiche détaillée de l'équipe CÏSCO (pdf) :

 

Download the detailled CÏSCO team sheet (pdf):

 
 

 

 

Publications

Dans la base de données : 50
  • 2018

  • Determining the Preferred Alkane Carbon Number (PACN) of nonionic surfactants using the PIT-slope method.
    Ontiveros Jesús F., Pierlot Christel, Catté Marianne, Salager Jean-Louis, Aubry Jean-Marie.
    Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 536, pg. 30-37 (2018) DOI
     
  • Prediction of the equivalent alkane carbon number (EACN) of aprotic polar oils with COSMO-RS sigma-moments.
    Lukowicz Thomas, Illous Estelle, Nardello-Rataj Véronique, Aubry Jean-Marie.
    Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 536, pg. 53-59 (2018) DOI
     
  • Biosourced lauroyl poly(glycerol-succinate) oligoesters modified by copolymerizable solvents: A wasteless and eco-friendly surfactants properties enhancement.
    Agach Mickaël, Marinkovic Sinisa, Estrine Boris, Nardello-Rataj Véronique.
    Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 536, pg. 88-95 (2018) DOI
     
  • Revisiting the influence of carboxylic acids on emulsions and equilibrated SOW systems using the PIT-slope method.
    Ontiveros Jesús F., Nollet Maxime, Pierlot Christel, Nardello-Rataj Veronique.
    Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 536, pg. 191-197 (2018) DOI
     
  • Carnitine alkyl ester bromides as novel biosourced ionic liquids, cationic hydrotropes and surfactants.
    Häckl Katharina, Mühlbauer Andrea, Ontiveros Jesús F., Marinkovic Sinisa, Estrine Boris, Kunz Werner, Nardello-Rataj Véronique.
    Journal of Colloid and Interface Science, vol. 511, pg. 165-173 (2018) DOI
     
  • An eco-compatible pathway to new hydrotropes from tetraols.
    Herbinski Aurélien, Métay Estelle, Da Silva Eric, Illous Estelle, Aubry Jean-Marie, Lemaire Marc.
    Green Chemistry, (2018) DOI
     
  • Synthesis and Surfactant Properties of Nonionic Biosourced Alkylglucuronamides.
    Lebeuf Raphaël, Liu Chih-Yin, Pierlot Christel, Nardello-Rataj Véronique.
    ACS Sustainable Chemistry < Engineering, vol. 6, pg. 2758-2766 (2018) DOI
     
  • Trialkylamine-Catalyzed Aldolization of Unprotected 1,3-Dihydroxyacetone (DHA) toward C–C Bond-Linked Tetraol Surfactants.
    Zhu Biwen, Belmessieri Dorine, Ontiveros Jesús Fermin, Aubry Jean-Marie, Chen Guo-Rong, Duguet Nicolas, Lemaire Marc.
    ACS Sustainable Chemistry < Engineering, vol. 6, pg. 2630-2640 (2018) DOI
     
  • Emulsification of viscous alkyd resin by catastrophic phase inversion with nonionic surfactant.
    Pierlot Christel, Ontiveros Jesus F., Royer Maxime, Catté Marianne, Salager Jean-Louis.
    Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 536, pg. 113-124 (2018) DOI
     
  • Rheological properties of wormlike micellar gels formed by novel bio-based isosorbide surfactants.
    Kamada Miho, Pierlot Christel, Molinier Valérie, Aubry Jean-Marie, Aramaki Kenji.
    Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 536, pg. 82-87 (2018) DOI
     
  • Towards a new universal way to describe the required hydrophilic lipophilic balance of oils using the phase inversion temperature of C 10 E 4 /n-octane/water emulsions.
    Royer Maxime, Nollet Maxime, Catté Marianne, Collinet Marion, Pierlot Christel.
    Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 536, pg. 165-171 (2018) DOI
     
  • 2017

  • Supramolecular “Big Bang” in a Single-Ionic Surfactant/Water System Driven by Electrostatic Repulsion: From Vesicles to Micelles.
    Leclercq Loïc, Bauduin Pierre, Nardello-Rataj Véronique.
    Langmuir, vol. 33, pg. 3395-3403 (2017) DOI
     
  • Acidic/amphiphilic silica nanoparticles: new eco-friendly Pickering interfacial catalysis for biodiesel production.
    Yang Bingyu, Leclercq Loïc, Clacens Jean-Marc, Nardello-Rataj Véronique.
    Green Chem., vol. 19, pg. 4552-4562 (2017) DOI
     
  • Solvent- and base-free synthesis of wax esters from fatty acid methyl esters by consecutive one-pot, two-step catalysis.
    Nguyen D. H., Raffa G., Morin Y., Desset S., Capet F., Nardello-Rataj V., Dumeignil F., Gauvin R. M.
    Green Chemistry, vol. 19, pg. 5665-5673 (2017) DOI
     
  • Hydroquinone-Based Biarylic Polyphenols as Redox Organocatalysts for Dioxygen Reduction: Dramatic Effect of Orcinol Substituent on the Catalytic Activity.
    Lebeuf Raphaël, Nardello-Rataj Véronique, Aubry Jean-Marie.
    Advanced Synthesis < Catalysis, vol. 359, pg. 268-278 (2017) DOI
     
  • Optimization of CVD parameters for graphene synthesis through design of experiments.
    Papon Remi, Pierlot Christel, Sharma Subash, Shinde Sachin Maruti, Kalita Golap, Tanemura Masaki.
    physica status solidi (b), vol. 254, pg. 1600629 (2017) DOI
     
  • Computer aided framework for designing bio-based commodity molecules with enhanced properties.
    Gerbaud V., Teles Dos Santos M., Pandya N., Aubry J.M.
    Chemical Engineering Science, vol. 159, pg. 177-193 (2017) DOI
     
  • Synthesis, surfactant properties and antimicrobial activities of methyl glycopyranoside ethers.
    Belmessieri Dorine, Gozlan Charlotte, Duclos Marie-Christine, Molinier Valérie, Aubry Jean-Marie, Dumitrescu Oana, Lina Gérard, Redl Andreas, Duguet Nicolas, Lemaire Marc.
    European Journal of Medicinal Chemistry, vol. 128, pg. 98-106 (2017) DOI
     
  • Self-stratifying epoxy/silicone coatings.
    Beaugendre A., Degoutin S., Bellayer S., Pierlot C., Duquesne S., Casetta M., Jimenez M.
    Progress in Organic Coatings, vol. 103, pg. 101-110 (2017) DOI
     
  • Catalytic activity of primary and secondary driers towards the oxidation and hydroperoxide decomposition steps for the chemical drying of alkyd resin.
    Dubrulle L., Lebeuf R., Thomas L., Fressancourt-Collinet M., Nardello-Rataj V.
    Progress in Organic Coatings, vol. 104, pg. 141-151 (2017) DOI
     
  • Self-stratifying coatings: A review.
    Beaugendre A., Degoutin S., Bellayer S., Pierlot C., Duquesne S., Casetta M., Jimenez M.
    Progress in Organic Coatings, vol. 110, pg. 210-241 (2017) DOI
     
  • Optimization of the vegetable oil composition in alkyd resins: A kinetic approach based on FAMEs autoxidation.
    Dubrulle L., Lebeuf R., Fressancourt-Collinet M., Nardello-Rataj V.
    Progress in Organic Coatings, vol. 112, pg. 288-294 (2017) DOI
     
  • Predicting the Surface Tension of Liquids: Comparison of Four Modeling Approaches and Application to Cosmetic Oils.
    Goussard Valentin, Duprat François, Gerbaud Vincent, Ploix Jean-Luc, Dreyfus Gérard, Nardello-Rataj Véronique, Aubry Jean-Marie.
    Journal of Chemical Information and Modeling, vol. 57, pg. 2986-2995 (2017) DOI
     
  • 2016

  • Boosting effect of ortho-propenyl substituent on the antioxidant activity of natural phenols.
    Marteau Clémentine, Guitard Romain, Penverne Christophe, Favier Dominique, Nardello-Rataj Véronique, Aubry Jean-Marie.
    Food Chemistry, vol. 196, pg. 418-427 (2016) DOI
     
  • Pickering emulsions based on cyclodextrins: A smart solution for antifungal azole derivatives topical delivery.
    Leclercq Loïc, Nardello-Rataj Véronique.
    European Journal of Pharmaceutical Sciences, vol. 82, pg. 126-137 (2016) DOI
     
  • Preparation of amphiphilic sorbitan monoethers through hydrogenolysis of sorbitan acetals and evaluation as bio-based surfactants.
    Gozlan Charlotte, Deruer Elsa, Duclos Marie-Christine, Molinier Valérie, Aubry Jean-Marie, Redl Andreas, Duguet Nicolas, Lemaire Marc.
    Green Chem., (2016) DOI
     
  • Supramolecular assistance between cyclodextrins and didecyldimethylammonium chloride against enveloped viruses: Toward eco-biocidal formulations.
    Leclercq Loïc, Dewilde Anny, Aubry Jean-Marie, Nardello-Rataj Véronique.
    International Journal of Pharmaceutics, vol. 512, pg. 273-281 (2016) DOI
     
  • Aqueous solutions of didecyldimethylammonium chloride and octaethylene glycol monododecyl ether: Toward synergistic formulations against enveloped viruses.
    Nardello-Rataj Véronique, Leclercq Loïc.
    International Journal of Pharmaceutics, vol. 511, pg. 550-559 (2016) DOI
     
  • Smart medical textiles based on cyclodextrins for curative or preventive patient care.
    Leclercq L.
    Woodhead Publishing Series in Textiles, pg. 391-427 (2016) DOI
     
  • Theoretical and Kinetic Tools for Selecting Effective Antioxidants: Application to the Protection of Omega-3 Oils with Natural and Synthetic Phenols.
    Guitard Romain, Nardello-Rataj Véronique, Aubry Jean-Marie.
    International Journal of Molecular Sciences, vol. 17, pg. 1220 (2016) DOI
     
  • Acyl Poly(Glycerol-Succinic Acid) Oligoesters: Synthesis, Physicochemical and Functional Properties, and Biodegradability.
    Agach Mickaël, Marinkovic Sinisa, Estrine Boris, Nardello-Rataj Véronique.
    Journal of Surfactants and Detergents, vol. 19, pg. 933-941 (2016) DOI
     
  • Myricetin, rosmarinic and carnosic acids as superior natural antioxidant alternatives to α-tocopherol for the preservation of omega-3 oils.
    Guitard Romain, Paul Jean-François, Nardello-Rataj Véronique, Aubry Jean-Marie.
    Food Chemistry, vol. 213, pg. 284-295 (2016) DOI
     
  • Cone–Plate Rheometer as Reactor and Viscosity Probe for the Detection of Transitional Phase Inversion of Brij30–Isopropyl Myristate–Water Model Emulsion.
    Pierlot Christel, Ontiveros Jesus F., Catté Marianne, Salager Jean-Louis, Aubry Jean-Marie.
    Industrial < Engineering Chemistry Research, vol. 55, pg. 3990-3999 (2016) DOI
     
  • Solvo-Surfactant Properties of Dialkyl Glycerol Ethers: Application as Eco-Friendly Extractants of Plant Material through a Novel Hydrotropic Cloud Point Extraction (HCPE) Process.
    LEBEUF R, ILLOUS E, DUSSENNE C, MOLINIER V, SILVA E DA, LEMAIRE M, AUBRY J -M.
    ACS Sustainable Chem. Eng. , vol. 4(9), pg. 4815-4823 (2016) DOI
     
  • Interactions between cyclodextrins and cellular components: Towards greener medical applications?.
    Leclercq Loïc.
    Beilstein Journal of Organic Chemistry, vol. 12, pg. 2644-2662 (2016) DOI
     
  • Interactions underpinning the plasticization of a polymer matrix: a dynamic and structural analysis of DMP-plasticized cellulose acetate.
    Benazzouz Adrien, Dudognon Emeline, Correia Natália T., Molinier Valérie, Aubry Jean-Marie, Descamps Marc.
    Cellulose, vol. 24, pg. 487-503 (2016) DOI
     
  • One-Pot Synthesis of (+)-Nootkatone via Dark Singlet Oxygenation of Valencene: The Triple Role of the Amphiphilic Molybdate Catalyst.
    Hong Bing, Lebeuf Raphaël, Delbaere Stéphanie, Alsters Paul, Nardello-Rataj Véronique.
    Catalysts, vol. 6, pg. 184 (2016) DOI
     
  • Weighted fuzzy clustering for (fuzzy) constraints in multivariate image analysis–alternating least square of hyperspectral images.
    Hugelier Siewert, Firmani Patrizia, Devos Olivier, Moreau Myriam, Pierlot Christel, Marini Federico, Ruckebusch Cyril.
    Journal of Spectral Imaging, vol. 1 (2016) DOI
     
  • A “top-down” in silico approach for designing ad hoc bio-based solvents: application to glycerol-derived solvents of nitrocellulose.
    Moity Laurianne, Molinier Valérie, Benazzouz Adrien, Joossen Benjamin, Gerbaud Vincent, Aubry Jean-Marie.
    Green Chemistry, vol. 18, pg. 3239-3249 (2016) DOI
     
  • 2015

  • Synergy between bis(dimethyldioctylammonium) molybdate and tetraethylene glycol monooctyl ether: A winning combination for interfacial catalysis in thermo-controlled and switchable microemulsions.
    Hong Bing, Leclercq Loïc, Collinet-Fressancourt Marion, Lai Jonathan, Bauduin Pierre, Aubry Jean-Marie, Nardello-Rataj Véronique.
    Journal of Molecular Catalysis A: Chemical, vol. 397, pg. 142-149 (2015) DOI
     
  • Pickering Interfacial Catalysis for Biphasic Systems: From Emulsion Design to Green Reactions.
    Pera-Titus Marc, Leclercq Loïc, Clacens Jean-Marc, De Campo Floryan, Nardello-Rataj Véronique.
    Angewandte Chemie International Edition, vol. 54, pg. 2006-2021 (2015) DOI
     
  • Glycerol acetals and ketals as bio-based solvents: positioning in Hansen and COSMO-RS spaces, volatility and stability towards hydrolysis and autoxidation.
    Moity Laurianne, Benazzouz Adrien, Molinier Valérie, Nardello-Rataj Véronique, Elmkaddem Mohammed Kamal, de Caro Pascale, Thiébaud-Roux Sophie, Gerbaud Vincent, Marion Philippe, Aubry Jean-Marie.
    Green Chem., vol. 17, pg. 1779-1792 (2015) DOI
     
  • Structure–interfacial properties relationship and quantification of the amphiphilicity of well-defined ionic and non-ionic surfactants using the PIT-slope method.
    Ontiveros Jesús F., Pierlot Christel, Catté Marianne, Molinier Valérie, Salager Jean-Louis, Aubry Jean-Marie.
    Journal of Colloid and Interface Science, vol. 448, pg. 222-230 (2015) DOI
     
  • Dramatic influence of fragrance alcohols and phenols on the phase inversion temperature of the Brij30/n-octane/water system.
    Ontiveros Jesús F., Bouton François, Durand Morgan, Pierlot Christel, Quellet Christian, Nardello-Rataj Véronique, Aubry Jean-Marie.
    Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 478, pg. 54-61 (2015) DOI
     
  • Self-Assembled Polyoxometalates Nanoparticles as Pickering Emulsion Stabilizers.
    Leclercq Loïc, Mouret Adrien, Renaudineau Séverine, Schmitt Véronique, Proust Anna, Nardello-Rataj Véronique.
    The Journal of Physical Chemistry B, vol. 119, pg. 6326-6337 (2015) DOI
     
  • Rationalization and Prediction of the Equivalent Alkane Carbon Number (EACN) of Polar Hydrocarbon Oils with COSMO-RS σ-Moments.
    Lukowicz Thomas, Benazzouz Adrien, Nardello-Rataj Véronique, Aubry Jean-Marie.
    Langmuir, vol. 31, pg. 11220-11226 (2015) DOI
     
  • Nanometer-Size Polyoxometalate Anions Adsorb Strongly on Neutral Soft Surfaces.
    Naskar Bappaditya, Diat Olivier, Nardello-Rataj Véronique, Bauduin Pierre.
    The Journal of Physical Chemistry C, vol. 119, pg. 20985-20992 (2015) DOI
     
  • 2014

  • Haem extraction from peptidic hydrolysates of bovine haemoglobin using temperature sensitive C10E4/O/W microemulsion system.
    Ontiveros Jesus F., Froidevaux Renato, Dhulster Pascal, Salager Jean-Louis, Pierlot Christel.
    Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 454, pg. 135-143 (2014) DOI
     
  • 2013

  • Iodoetherification of Isosorbide-Derived Glycals: Access to a Variety ofO-Alkyl orO-Aryl Isosorbide Derivatives.
    Berini Christophe, Lavergne Aurélie, Molinier Valérie, Capet Frédéric, Deniau Eric, Aubry Jean-Marie.
    European Journal of Organic Chemistry, vol. 2013, pg. 1937-1949 (2013) DOI
     
  • Selective Oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran over Intercalated Vanadium Phosphate Oxides.
    Grasset Fabien, Katryniok Benjamin, Paul Sebastien, Nardello-Rataj Veronique, Pera-Titus Marc, Clacens Jean-Marc, Decampo Floryan, Dumeignil Franck Yves.
    RSC Advances, vol. 3, pg. 9942-9958 (2013) DOI