Equipe MATHYB - MATHYB team

Matériaux hybrides

Hybrid materials

Mots-clefs - Key words

Matériaux microporeux, Metal-Organic Framework (MOF), Polymères de coordination, Cluster polyoxométallate (POM), Complexes de coordination avec les éléments f

Microporous Materials, Metal-Organic Framework (MOF), coordination polymer, Polyoxometalate (POM) clusters, Coordination complexes with f-elements

 

 MEMBRES DE L'EQUIPE - TEAM MEMBERS
Nom Fonction Institution Web
Loiseau T. Directeur de Recherches
CNRS
page
Duval S. Maître de Conférences Univ. Lille page
Henry N.. Maître de Conférences ENSCL page
Volkringer C. Professeur ENSCL page

 

  MOT DU RESPONSABLE D’ÉQUIPE       TEAM LEADER FOREWORD  
  Créée en septembre 2017, l’équipe MATHYB comprend 4 permanents et 3 doctorants & post-doctorants. Nos activités portent sur la synthèse de solides hybrides organique-inorganique de type polymère de coordination ou Metal-Organic Framework (MOF), et d’espèces moléculaires de type polyoxométallate (POM). Nous nous appuyons sur des compétences sur la condensation en chimie inorganique afin de proposer des systèmes chimiques « sur mesure » avec une dimensionnalité et nucléarité des espèces inorganiques bien définies. Nous explorons cette chimie de coordination dans le but d’élaborer de nouveaux matériaux nanostructurés multifonctionnels avec des propriétés de porosité afin de proposer de nouvelles plateformes pour l’adsorption de gaz, la catalyse et la dépollution. Nous exploitons également nos connaissances de la chimie de coordination avec les métaux lourds afin d’appréhender les interactions de ces éléments avec les molécules complexantes (naturelles ou polluantes) provenant de l’écosystème.

Thierry Loiseau, Directeur de Recherches CNRS

      Created in September 2017, the MATHYB team includes 4 permanent staff and 3 PhD & post-doctoral students. Our activities focus on the synthesis of organic-inorganic hybrid solids of Coordination polymer or Metal-Organic Framework (MOF) type and, molecular species of polyoxometallate (POM) type. We rely on condensation skills in inorganic chemistry to propose «tailor-made» chemical systems with dimensionality and nuclearity of well-defined inorganic species. We are exploring this coordination chemistry in order to develop new multifunctional nanostructured materials with porosity properties in order to propose new platforms for gas sorption or catalysis. We also exploit our knowledge of coordination chemistry with heavy metals in order to understand the interactions of these elements with the complexing molecules (natural or polluting) coming from the ecosystem.

Thierry Loiseau, CNRS Research Director

 
             
  CHIFFRES CLES       KEY FIGURES  
  4 chercheurs et enseignants-chercheurs
8 publications par an en moyenne
1 contrat ANR / 1 contrat ANR PIA (MIRE)
      4 researchers
8 publications per year in average
1 ANR contract, 1 ANR PIA (MIRE) contract
 

 

Téléchargez la fiche détaillée de l'équipe MATHYB (pdf) :

 

Download the detailled MATHYB team sheet (pdf):

 
 

 

Publications

Dans la base de données : 44
  • 2018

  • Dynamic sorption properties of Metal-Organic Frameworks for the capture of methyl iodide.
    Chebbi Mouheb, Azambre Bruno, Volkringer Christophe, Loiseau Thierry.
    Microporous and Mesoporous Materials, vol. 259, pg. 244-254 (2018) DOI
     
  • 2017

  • Total Synthesis of (–)-Herbaric Acid through Organocatalyzed Asymmetric Halolactonization of Acrylate-Type Benzoic Acids.
    Deniau Eric, Michon Christophe, Gelat Fabien, Lebrun Stéphane, Henry Natacha, Agbossou-Niedercorn Francine.
    Synlett, vol. 28, pg. 225-230 (2017) DOI
     
  • Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in porous metal–organic framework MIL-100(Al) from water: selectivity and imaging of embedded nanoparticles.
    Falaise Clément, Volkringer Christophe, Giovine Raynald, Prelot Bénédicte, Huve Marielle, Loiseau Thierry.
    Dalton Trans., vol. 46, pg. 12010-12014 (2017) DOI
     
  • NMR crystallography to probe the breathing effect of the MIL-53(Al) metal–organic framework using solid-state NMR measurements of 13C–27Al distances.
    Giovine Raynald, Volkringer Christophe, Trébosc Julien, Amoureux Jean-Paul, Loiseau Thierry, Lafon Olivier, Pourpoint Frédérique.
    Acta Crystallographica Section C Structural Chemistry, vol. 73, pg. 176-183 (2017) DOI
     
  • Solid-State NMR Spectroscopy Proves the Presence of Penta-coordinated Sc Sites in MIL-100(Sc).
    Giovine Raynald, Volkringer Christophe, Ashbrook Sharon E., Trébosc Julien, McKay David, Loiseau Thierry, Amoureux Jean-Paul, Lafon Olivier, Pourpoint Frédérique.
    Chemistry - A European Journal, vol. 23, pg. 9525-9534 (2017) DOI
     
  • Study of Xenon Mobility in the Two Forms of MIL-53(Al) Using Solid-State NMR Spectroscopy.
    Giovine Raynald, Volkringer Christophe, Springuel-Huet Marie-Anne, Nossov Andrei, Blanc Frédéric, Trébosc Julien, Loiseau Thierry, Amoureux Jean-Paul, Lafon Olivier, Pourpoint Frédérique.
    The Journal of Physical Chemistry C, vol. 121, pg. 19262-19268 (2017) DOI
     
  • Synthesis of a large dodecameric cerium cluster stabilized by the [SiW 9 O 34 ] 10− polyoxometalate.
    Duval Sylvain, Roussel Pascal, Loiseau Thierry.
    Inorganic Chemistry Communications, vol. 83, pg. 52-54 (2017) DOI
     
  • Structural studies of a series of uranyl alkylacetamides and piracetam complexes obtained in nitric acid aqueous solution.
    Loubert Gaël, Volkringer Christophe, Henry Natacha, Arab-Chapelet Bénédicte, Delahaye Thibaud, Loiseau Thierry.
    Polyhedron, vol. 138, pg. 7-12 (2017) DOI
     
  • Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium.
    Martin Nicolas P., März Juliane, Volkringer Christophe, Henry Natacha, Hennig Christoph, Ikeda-Ohno Atsushi, Loiseau Thierry.
    Inorganic Chemistry, vol. 56, pg. 2902-2913 (2017) DOI
     
  • On shrinkage and structure changes of pure and blended Portland concretes.
    Zhang Yao, Davy Catherine A., Tricot Gregory, Albert-Mercier Cyrille, Henry Natacha, Bertier Pieter, Cazaux Frédéric, Damidot Denis, Bourbon Xavier.
    Journal of the American Ceramic Society, vol. 100, pg. 4131-4152 (2017) DOI
     
  • 2016

  • Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers.
    Martin Nicolas P., Volkringer Christophe, Falaise Clément, Henry Natacha, Loiseau Thierry.
    Crystal Growth < Design, vol. 16, pg. 1667-1678 (2016) DOI
     
  • Study of the reaction mechanisms involved in the formation of zirconium oxycarbide from Metal-Organic Frameworks (MOFs) precursors.
    David Jeremy, Trolliard Gilles, Volkringer Christophe, Loiseau Thierry, Masson Olivier, Maître Alexandre.
    Journal of Alloys and Compounds, vol. 680, pg. 571-585 (2016) DOI
     
  • A new series of trivalent lanthanide (Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy) coordination polymers with a 1,2-cyclohexanedicarboxylate ligand: synthesis, crystal structure, luminescence and catalytic properties.
    Russell Samantha E., Gosset Cyrille, Agache Xavier, Volkringer Christophe, Henry Natacha, Decadt Roel, Van Deun Rik, Visseaux Marc, Loiseau Thierry.
    CrystEngComm, vol. 18, pg. 3594-3605 (2016) DOI
     
  • Synthesis, Structure, and Antiproliferative Activity of Ruthenium(II) Arene Complexes of Indenoisoquinoline Derivatives.
    Wambang Nathalie, Schifano-Faux Nadège, Martoriati Alain, Henry Natacha, Baldeyrou Brigitte, Bal-Mahieu Christine, Bousquet Till, Pellegrini Sylvain, Meignan Samuel, Cailliau Katia, Goossens Jean-François, Bodart Jean-François, T. Ndifon Peter, Pélinski Lydie.
    Organometallics, vol. 35, pg. 2868-2872 (2016) DOI
     
  • Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits.
    Martin Nicolas P., Falaise Clément, Volkringer Christophe, Henry Natacha, Farger Pierre, Falk Camille, Delahaye Emilie, Rabu Pierre, Loiseau Thierry.
    Inorganic Chemistry, vol. 55, pg. 8697-8705 (2016) DOI
     
  • Influence of the pH over the condensation of tetravalent cerium cations for a Ce - [A-a-SiW9O34]10- association leading to the formation of {Ce6O4(OH)4} core..
    Duval Sylvain, Trivelli Xavier, Roussel Pascal, Loiseau Thierry.
    European Journal of Inorganic Chemistry, (2016) DOI
     
  • Stability of metal–organic frameworks under gamma irradiation.
    Volkringer C., Falaise C., Devaux P., Giovine R., Stevenson V., Pourpoint F., Lafon O., Osmond M., Jeanjacques C., Marcillaud B., Sabroux J. C., Loiseau T.
    Chemical Communications, vol. 52, pg. 12502-12505 (2016) DOI
     
  • Series of Hydrated Heterometallic Uranyl-Cobalt(II) Coordination Polymers with Aromatic Polycarboxylate Ligands: Formation of U═O—Co Bonding upon Dehydration Process.
    Falaise Clément, Delille Jason, Volkringer Christophe, Vezin Hervé, Rabu Pierre, Loiseau Thierry.
    Inorganic Chemistry, vol. 55, pg. 10453-10466 (2016) DOI
     
  • Iodine sequestration by thiol-modified MIL-53(Al).
    Munn Alexis S., Millange Franck, Frigoli Michel, Guillou Nathalie, Falaise Clément, Stevenson Victoria, Volkringer Christophe, Loiseau Thierry, Cibin Giannantonio, Walton Richard I.
    CrystEngComm, vol. 18, pg. 8108-8114 (2016) DOI
     
  • 2015

  • Coordination polymers of uranium(iv) terephthalates.
    Falaise Clément, Assen Ayalew, Mihalcea Ionut, Volkringer Christophe, Mesbah Adel, Dacheux Nicolas, Loiseau Thierry.
    Dalton Trans., vol. 44, pg. 2639-2649 (2015) DOI
     
  • Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System.
    Falaise Clément, Charles Jean-Sébastien, Volkringer Christophe, Loiseau Thierry.
    Inorganic Chemistry, vol. 54, pg. 2235-2242 (2015) DOI
     
  • Synthesis of zirconium oxycarbide powders using Metal-Organic Framework (MOF) compounds as precursors.
    David Jérémy, Trolliard Gilles, Volkringer Christophe, Loiseau Thierry, Maître Alexandre.
    RSC Adv., vol. 5, pg. 51650-51661 (2015) DOI
     
  • Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands.
    Falaise Clément, Delille Jason, Volkringer Christophe, Loiseau Thierry.
    European Journal of Inorganic Chemistry, vol. 2015, pg. 2813-2821 (2015) DOI
     
  • Stabilization of Tetravalent 4f (Ce), 5d (Hf), or 5f (Th, U) Clusters by the [α-SiW9O34]10–Polyoxometalate.
    Duval Sylvain, Béghin Sébastien, Falaise Clément, Trivelli Xavier, Rabu Pierre, Loiseau Thierry.
    Inorganic Chemistry, vol. 54, pg. 8271-8280 (2015) DOI
     
  • Ex-Situ Kinetic Investigations of the Formation of the Poly-Oxo Cluster U38.
    Falaise Clément, Volkringer Christophe, Hennig Christoph, Loiseau Thierry.
    Chemistry - A European Journal, vol. 21, pg. 16654-16664 (2015) DOI
     
  • Luminescent Lanthanide Metal Organic Frameworks for cis-Selective Isoprene Polymerization Catalysis.
    Russell Samantha, Loiseau Thierry, Volkringer Christophe, Visseaux Marc.
    Inorganics, vol. 3, pg. 467-481 (2015) DOI
     
  • B-α-[AsW9O33]9−polyoxometalates incorporating hexanuclear uranium {U6O8}-like clusters bearing the UIVform or unprecedented mixed valence UIV/UVIinvolving direct UVIO–UIVbonding.
    Duval Sylvain, Sobanska Sophie, Roussel Pascal, Loiseau Thierry.
    Dalton Trans., vol. 44, pg. 19772-19776 (2015) DOI
     
  • Crystal chemistry of aluminium carboxylates: From molecular species towards porous infinite three-dimensional networks.
    Loiseau Thierry, Volkringer Christophe, Haouas Mohamed, Taulelle Francis, Férey Gérard.
    Comptes Rendus Chimie, vol. 18, pg. 1350-1369 (2015) DOI
     
  • The Direct Heat Measurement of Mechanical Energy Storage Metal-Organic Frameworks.
    Rodriguez Julien, Beurroies Isabelle, Loiseau Thierry, Denoyel Renaud, Llewellyn Philip L.
    Angewandte Chemie International Edition, vol. 54, pg. 4626-4630 (2015) DOI
     
  • 2014

  • Isolation of thorium benzoate polytypes with discrete ThO8 square antiprismatic units involved in chain-like assemblies.
    Falaise Clément, Volkringer Christophe, Loiseau Thierry.
    Inorganic Chemistry Communications, vol. 39, pg. 26-30 (2014) DOI
     
  • Crystal structures of tetravalent uranium fluorides obtained in the presence of hydrazine from uranyl source.
    Olchowka Jakub, Volkringer Christophe, Henry Natacha, Loiseau Thierry.
    Journal of Fluorine Chemistry, vol. 159, pg. 1-7 (2014) DOI
     
  • The crystal chemistry of uranium carboxylates.
    Loiseau Thierry, Mihalcea Ionut, Henry Natacha, Volkringer Christophe.
    Coordination Chemistry Reviews, vol. 266-267, pg. 69-109 (2014) DOI
     
  • Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules.
    Mihalcea Ionut, Henry Natacha, Loiseau Thierry.
    European Journal of Inorganic Chemistry, vol. 2014, pg. 1322-1332 (2014) DOI
     
  • Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers.
    Mihalcea Ionut, Falaise Clément, Volkringer Christophe, Henry Natacha, Loiseau Thierry.
    Inorganic Chemistry Communications, vol. 44, pg. 63-66 (2014) DOI
     
  • Probing 27Al–13C proximities in metal–organic frameworks using dynamic nuclear polarization enhanced NMR spectroscopy.
    Pourpoint Frédérique, Thankamony Aany Sofia Lilly, Volkringer Christophe, Loiseau Thierry, Trébosc Julien, Aussenac Fabien, Carnevale Diego, Bodenhausen Geoffrey, Vezin Hervé, Lafon Olivier, Amoureux Jean-Paul.
    Chemical Communications, vol. 50, pg. 933 (2014) DOI
     
  • 2013

  • Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid-State Topotactic Transformation upon Dehydration.
    Olchowka Jakub, Falaise Clément, Volkringer Christophe, Henry Natacha, Loiseau Thierry.
    Chemistry - A European Journal, vol. 19, pg. 2012-2022 (2013) DOI
     
  • Crystal structures of 2,2′:6′,2″-terpyridine uranyl chlorides molecular assemblies and their luminescence signatures.
    Lhoste Jérôme, Henry Natacha, Loiseau Thierry, Guyot Yannick, Abraham Francis.
    Polyhedron, vol. 50, pg. 321-327 (2013) DOI
     
  • Three-Dimensional MOF-Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8).
    Falaise Clément, Volkringer Christophe, Vigier Jean-François, Henry Natacha, Beaurain Arnaud, Loiseau Thierry.
    Chemistry - A European Journal, vol. 19, pg. 5324-5331 (2013) DOI
     
  • Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O.
    Olchowka Jakub, Volkringer Christophe, Henry Natacha, Loiseau Thierry.
    European Journal of Inorganic Chemistry, vol. 2013, pg. 2109-2114 (2013) DOI
     
  • Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U4O4} and Hexanuclear {U6O4(OH)4} Motifs.
    Falaise Clément, Volkringer Christophe, Loiseau Thierry.
    Crystal Growth < Design, vol. 13, pg. 3225-3231 (2013) DOI
     
  • Capture of iodine in highly stable metal–organic frameworks: a systematic study.
    Falaise Clément, Volkringer Christophe, Facqueur Jacques, Bousquet Till, Gasnot Laurent, Loiseau Thierry.
    Chemical Communications, vol. 49, pg. 10320 (2013) DOI
     
  • Isolation of the Large {Actinide}38Poly-oxo Cluster with Uranium.
    Falaise Clément, Volkringer Christophe, Vigier Jean-François, Beaurain Arnaud, Roussel Pascal, Rabu Pierre, Loiseau Thierry.
    Journal of the American Chemical Society, vol. 135, pg. 15678-15681 (2013) DOI
     
  • Nanoporous Solids: How Do They Form? An In Situ Approach.
    Férey Gérard, Haouas Mohamed, Loiseau Thierry, Taulelle Francis.
    Chemistry of Materials, vol. 26, pg. 299-309 (2013) DOI
     
  • Synthesis and structural characterization of metal–organic frameworks with the mellitate linker M2(OH)2[C12O12H2]·2H2O (M = Al, Ga, In) MIL-116.
    Volkringer Christophe, Loiseau Thierry, Guillou Nathalie, Férey Gérard, Popov Dmitry, Burghammer Manfred, Riekel Christian.
    Solid State Sciences, vol. 26, pg. 38-44 (2013) DOI