MATHYB team

Hybrid materials

Key words

Microporous Materials, Metal-Organic Framework (MOF), coordination polymer, Polyoxometalate (POM) clusters, Coordination complexes with f-elements

 

  TEAM MEMBERS
Name Function Employer Web page
Loiseau T. CNRS Research Director CNRS
page
Duval S. Assistant Professor Univ. Lille page
Henry N. Assistant Professor Univ. Lille
page
Volkringer C. Professor ENSCL page

 

  TEAM LEADER FOREWORD  
 

Created in September 2017, the MATHYB team includes 4 permanent staff and 3 PhD & post-doctoral students. Our activities focus on the synthesis of organic-inorganic hybrid solids of Coordination polymer or Metal-Organic Framework (MOF) type and, molecular species of polyoxometallate (POM) type. We rely on condensation skills in inorganic chemistry to propose «tailor-made» chemical systems with dimensionality and nuclearity of well-defined inorganic species. We are exploring this coordination chemistry in order to develop new multifunctional nanostructured materials with porosity properties in order to propose new platforms for gas sorption or catalysis. We also exploit our knowledge of coordination chemistry with heavy metals in order to understand the interactions of these elements with the complexing molecules (natural or polluting) coming from the ecosystem.

 

Thierry Loiseau, CNRS Research Director

 
     
  KEY FIGURES  
  4 researchers
8 publications per year in average
1 ANR contract, 1 ANR PIA (MIRE) contract
 

 

 

Download the detailled MATHYB team leaflet (pdf):

 

 

Publications

Publications in the database: 58 (since 2013)
  • 2018

  • The Surprising Stability of Cu3(btc)2 Metal–Organic Framework under Steam Flow at High Temperature.
    Giovine Raynald, Pourpoint Frédérique, Duval Sylvain, Lafon Olivier, Amoureux Jean-Paul, Loiseau Thierry, Volkringer Christophe.
    Crystal Growth < Design, vol. 18, pg. 6681-6693 (2018) DOI
     
  • Bottom-up synthesis of functionalized {Ce4(SiW9O34)2(L)2} polyoxometalates.
    DUFAYE Maxime, Duval Sylvain, Nursiah Kelvinraj, Stoclet Grégory, Trivelli Xavier, Loiseau Thierry.
    CrystEngComm, vol. 20, pg. 7144 (2018) DOI
     
  • {Np38} clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides.
    Martin Nicolas P., Volkringer Christophe, Roussel Pascal, März Juliane, Hennig Christoph, Loiseau Thierry, Ikeda-Ohno Atsushi.
    Chemical Communications, vol. 54, pg. 10060 (2018) DOI
     
  • Complexation of tetravalent uranium cations by the As4W40O140 cryptand.
    DUFAYE Maxime, Duval Sylvain, Hirsou Bastien, Stoclet Grégory, Loiseau Thierry.
    CrystEngComm, vol. 20, pg. 5500 (2018) DOI
     
  • A DFT study of RuO4 interactions with porous materials: metal–organic frameworks (MOFs) and zeolites.
    Chibani Siwar, Badawi Michael, Loiseau Thierry, Volkringer Christophe, Cantrel Laurent, Paul Jean-François.
    Physical Chemistry Chemical Physics, vol. 20, pg. 16770 (2018) DOI
     
  • Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np6O8} hexanuclear clusters.
    Martin N. P., März J., Feuchter H., Duval S., Roussel P., Henry N., Ikeda-Ohno A., Loiseau T., Volkringer C.
    Chemical Communications, vol. 54, pg. 6979-6982 (2018) DOI
     
  • Formation of a new type of uranium(iv) poly-oxo cluster {U38} based on a controlled release of water via esterification reaction.
    Martin Nicolas P., Volkringer Christophe, Henry Natacha, Trivelli Xavier, Stoclet Grégory, Ikeda-Ohno Atsushi, Loiseau Thierry.
    Chemical Science, vol. 9, pg. 5021-5032 (2018) DOI
     
  • Undulated oxo-centered layers in PbLn 3 O 4 (VO 4 ) (Ln= La and Nd) and relationship with Nd 4 O 4 (GeO 4 ).
    Colmont Marie, Mentré Olivier, Henry Natacha, Pautrat Alain, Leclercq Bastien, Capet Frédéric, Djelal Nora, Roussel Pascal.
    Journal of Solid State Chemistry, vol. 260, pg. 101-105 (2018) DOI
     
  • Carbazole-based compounds as photoinitiators for free radical and cationic polymerization upon near visible light illumination.
    Al Mousawi Assi, Arar Ahmad, Ibrahim-Ouali Malika, Duval Sylvain, Dumur Frédéric, Garra Patxi, Toufaily Joumana, Hamieh Tayssir, Graff Bernadette, Gigmes Didier, Fouassier Jean-Pierre, Lalevée Jacques.
    Photochemical < Photobiological Sciences, vol. 17, pg. 578-585 (2018) DOI
     
  • Molecular Assemblies of a Series of Mixed Tetravalent Uranium and Trivalent Lanthanide Complexes Associated with the Dipicolinate Ligand, in Aqueous Medium.
    Martin Nicolas P., Volkringer Christophe, Henry Natacha, Duval Sylvain, Mara Dimitrije, Van Deun Rik, Loiseau Thierry.
    Crystal Growth < Design, vol. 18, pg. 2165-2179 (2018) DOI
     
  • Research Works on Iodine and Ruthenium Behavior in Severe Accident Conditions.
    Cantrel Laurent, Albiol Thierry, Bosland Loïc, Colombani Juliette, Cousin Frédéric, Grégoire Anne-Cécile, Leroy Olivia, Morin Sandrine, Mun Christian, Ohnet Marie-Noëlle, Souvi Sidi, Monsanglant-Louvet Céline, Louis Florent, Azambre Bruno, Volkringer Christophe.
    Journal of Nuclear Engineering and Radiation Science, vol. 4, pg. 020903 (2018) DOI
     
  • Dynamic sorption properties of Metal-Organic Frameworks for the capture of methyl iodide.
    Chebbi Mouheb, Azambre Bruno, Volkringer Christophe, Loiseau Thierry.
    Microporous and Mesoporous Materials, vol. 259, pg. 244-254 (2018) DOI
     
  • 2017

  • On shrinkage and structure changes of pure and blended Portland concretes.
    Zhang Yao, Davy Catherine A., Tricot Gregory, Albert-Mercier Cyrille, Henry Natacha, Bertier Pieter, Cazaux Frédéric, Damidot Denis, Bourbon Xavier.
    Journal of the American Ceramic Society, vol. 100, pg. 4131-4152 (2017) DOI
     
  • Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium.
    Martin Nicolas P., März Juliane, Volkringer Christophe, Henry Natacha, Hennig Christoph, Ikeda-Ohno Atsushi, Loiseau Thierry.
    Inorganic Chemistry, vol. 56, pg. 2902-2913 (2017) DOI
     
  • Structural studies of a series of uranyl alkylacetamides and piracetam complexes obtained in nitric acid aqueous solution.
    Loubert Gaël, Volkringer Christophe, Henry Natacha, Arab-Chapelet Bénédicte, Delahaye Thibaud, Loiseau Thierry.
    Polyhedron, vol. 138, pg. 7-12 (2017) DOI
     
  • Synthesis of a large dodecameric cerium cluster stabilized by the [SiW 9 O 34 ] 10− polyoxometalate.
    Duval Sylvain, Roussel Pascal, Loiseau Thierry.
    Inorganic Chemistry Communications, vol. 83, pg. 52-54 (2017) DOI
     
  • Study of Xenon Mobility in the Two Forms of MIL-53(Al) Using Solid-State NMR Spectroscopy.
    Giovine Raynald, Volkringer Christophe, Springuel-Huet Marie-Anne, Nossov Andrei, Blanc Frédéric, Trébosc Julien, Loiseau Thierry, Amoureux Jean-Paul, Lafon Olivier, Pourpoint Frédérique.
    The Journal of Physical Chemistry C, vol. 121, pg. 19262-19268 (2017) DOI
     
  • Solid-State NMR Spectroscopy Proves the Presence of Penta-coordinated Sc Sites in MIL-100(Sc).
    Giovine Raynald, Volkringer Christophe, Ashbrook Sharon E., Trébosc Julien, McKay David, Loiseau Thierry, Amoureux Jean-Paul, Lafon Olivier, Pourpoint Frédérique.
    Chemistry - A European Journal, vol. 23, pg. 9525-9534 (2017) DOI
     
  • NMR crystallography to probe the breathing effect of the MIL-53(Al) metal–organic framework using solid-state NMR measurements of 13C–27Al distances.
    Giovine Raynald, Volkringer Christophe, Trébosc Julien, Amoureux Jean-Paul, Loiseau Thierry, Lafon Olivier, Pourpoint Frédérique.
    Acta Crystallographica Section C Structural Chemistry, vol. 73, pg. 176-183 (2017) DOI
     
  • Capture of actinides (Th4+, [UO2]2+) and surrogating lanthanide (Nd3+) in porous metal–organic framework MIL-100(Al) from water: selectivity and imaging of embedded nanoparticles.
    Falaise Clément, Volkringer Christophe, Giovine Raynald, Prelot Bénédicte, Huve Marielle, Loiseau Thierry.
    Dalton Trans., vol. 46, pg. 12010-12014 (2017) DOI
     
  • Total Synthesis of (–)-Herbaric Acid through Organocatalyzed Asymmetric Halolactonization of Acrylate-Type Benzoic Acids.
    Deniau Eric, Michon Christophe, Gelat Fabien, Lebrun Stéphane, Henry Natacha, Agbossou-Niedercorn Francine.
    Synlett, vol. 28, pg. 225-230 (2017) DOI
     
  • 2016

  • Iodine sequestration by thiol-modified MIL-53(Al).
    Munn Alexis S., Millange Franck, Frigoli Michel, Guillou Nathalie, Falaise Clément, Stevenson Victoria, Volkringer Christophe, Loiseau Thierry, Cibin Giannantonio, Walton Richard I.
    CrystEngComm, vol. 18, pg. 8108-8114 (2016) DOI
     
  • Series of Hydrated Heterometallic Uranyl-Cobalt(II) Coordination Polymers with Aromatic Polycarboxylate Ligands: Formation of U═O—Co Bonding upon Dehydration Process.
    Falaise Clément, Delille Jason, Volkringer Christophe, Vezin Hervé, Rabu Pierre, Loiseau Thierry.
    Inorganic Chemistry, vol. 55, pg. 10453-10466 (2016) DOI
     
  • Stability of metal–organic frameworks under gamma irradiation.
    Volkringer C., Falaise C., Devaux P., Giovine R., Stevenson V., Pourpoint F., Lafon O., Osmond M., Jeanjacques C., Marcillaud B., Sabroux J. C., Loiseau T.
    Chemical Communications, vol. 52, pg. 12502-12505 (2016) DOI
     
  • Influence of the pH over the condensation of tetravalent cerium cations for a Ce - [A-a-SiW9O34]10- association leading to the formation of {Ce6O4(OH)4} core..
    Duval Sylvain, Trivelli Xavier, Roussel Pascal, Loiseau Thierry.
    European Journal of Inorganic Chemistry, (2016) DOI
     
  • Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits.
    Martin Nicolas P., Falaise Clément, Volkringer Christophe, Henry Natacha, Farger Pierre, Falk Camille, Delahaye Emilie, Rabu Pierre, Loiseau Thierry.
    Inorganic Chemistry, vol. 55, pg. 8697-8705 (2016) DOI
     
  • Synthesis, Structure, and Antiproliferative Activity of Ruthenium(II) Arene Complexes of Indenoisoquinoline Derivatives.
    Wambang Nathalie, Schifano-Faux Nadège, Martoriati Alain, Henry Natacha, Baldeyrou Brigitte, Bal-Mahieu Christine, Bousquet Till, Pellegrini Sylvain, Meignan Samuel, Cailliau Katia, Goossens Jean-François, Bodart Jean-François, T. Ndifon Peter, Pélinski Lydie.
    Organometallics, vol. 35, pg. 2868-2872 (2016) DOI
     
  • A new series of trivalent lanthanide (Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy) coordination polymers with a 1,2-cyclohexanedicarboxylate ligand: synthesis, crystal structure, luminescence and catalytic properties.
    Russell Samantha E., Gosset Cyrille, Agache Xavier, Volkringer Christophe, Henry Natacha, Decadt Roel, Van Deun Rik, Visseaux Marc, Loiseau Thierry.
    CrystEngComm, vol. 18, pg. 3594-3605 (2016) DOI
     
  • Study of the reaction mechanisms involved in the formation of zirconium oxycarbide from Metal-Organic Frameworks (MOFs) precursors.
    David Jeremy, Trolliard Gilles, Volkringer Christophe, Loiseau Thierry, Masson Olivier, Maître Alexandre.
    Journal of Alloys and Compounds, vol. 680, pg. 571-585 (2016) DOI
     
  • Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers.
    Martin Nicolas P., Volkringer Christophe, Falaise Clément, Henry Natacha, Loiseau Thierry.
    Crystal Growth < Design, vol. 16, pg. 1667-1678 (2016) DOI
     
  • 2015

  • The Direct Heat Measurement of Mechanical Energy Storage Metal-Organic Frameworks.
    Rodriguez Julien, Beurroies Isabelle, Loiseau Thierry, Denoyel Renaud, Llewellyn Philip L.
    Angewandte Chemie International Edition, vol. 54, pg. 4626-4630 (2015) DOI
     
  • Crystal chemistry of aluminium carboxylates: From molecular species towards porous infinite three-dimensional networks.
    Loiseau Thierry, Volkringer Christophe, Haouas Mohamed, Taulelle Francis, Férey Gérard.
    Comptes Rendus Chimie, vol. 18, pg. 1350-1369 (2015) DOI
     
  • B-α-[AsW9O33]9−polyoxometalates incorporating hexanuclear uranium {U6O8}-like clusters bearing the UIVform or unprecedented mixed valence UIV/UVIinvolving direct UVIO–UIVbonding.
    Duval Sylvain, Sobanska Sophie, Roussel Pascal, Loiseau Thierry.
    Dalton Trans., vol. 44, pg. 19772-19776 (2015) DOI
     
  • Luminescent Lanthanide Metal Organic Frameworks for cis-Selective Isoprene Polymerization Catalysis.
    Russell Samantha, Loiseau Thierry, Volkringer Christophe, Visseaux Marc.
    Inorganics, vol. 3, pg. 467-481 (2015) DOI
     
  • Ex-Situ Kinetic Investigations of the Formation of the Poly-Oxo Cluster U38.
    Falaise Clément, Volkringer Christophe, Hennig Christoph, Loiseau Thierry.
    Chemistry - A European Journal, vol. 21, pg. 16654-16664 (2015) DOI
     
  • Stabilization of Tetravalent 4f (Ce), 5d (Hf), or 5f (Th, U) Clusters by the [α-SiW9O34]10–Polyoxometalate.
    Duval Sylvain, Béghin Sébastien, Falaise Clément, Trivelli Xavier, Rabu Pierre, Loiseau Thierry.
    Inorganic Chemistry, vol. 54, pg. 8271-8280 (2015) DOI
     
  • Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands.
    Falaise Clément, Delille Jason, Volkringer Christophe, Loiseau Thierry.
    European Journal of Inorganic Chemistry, vol. 2015, pg. 2813-2821 (2015) DOI
     
  • Synthesis of zirconium oxycarbide powders using Metal-Organic Framework (MOF) compounds as precursors.
    David Jérémy, Trolliard Gilles, Volkringer Christophe, Loiseau Thierry, Maître Alexandre.
    RSC Adv., vol. 5, pg. 51650-51661 (2015) DOI
     
  • Coordination polymers of uranium(iv) terephthalates.
    Falaise Clément, Assen Ayalew, Mihalcea Ionut, Volkringer Christophe, Mesbah Adel, Dacheux Nicolas, Loiseau Thierry.
    Dalton Trans., vol. 44, pg. 2639-2649 (2015) DOI
     
  • Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System.
    Falaise Clément, Charles Jean-Sébastien, Volkringer Christophe, Loiseau Thierry.
    Inorganic Chemistry, vol. 54, pg. 2235-2242 (2015) DOI
     
  • 2014

  • Tetracarboxylate Ligands as New Chelates Supporting Copper(II) Paddlewheel-Like Structures.
    Gomila Antoine, Duval Sylvain, Besnard Céline, Krämer Karl W., Liu Shi-Xia, Decurtins Silvio, Williams Alan F.
    Inorganic Chemistry, vol. 53, pg. 2683-2691 (2014) DOI
     
  • Nanoporous Solids: How Do They Form? An In Situ Approach.
    Férey Gérard, Haouas Mohamed, Loiseau Thierry, Taulelle Francis.
    Chemistry of Materials, vol. 26, pg. 299-309 (2014) DOI
     
  • Isolation of thorium benzoate polytypes with discrete ThO8 square antiprismatic units involved in chain-like assemblies.
    Falaise Clément, Volkringer Christophe, Loiseau Thierry.
    Inorganic Chemistry Communications, vol. 39, pg. 26-30 (2014) DOI
     
  • Crystal structures of tetravalent uranium fluorides obtained in the presence of hydrazine from uranyl source.
    Olchowka Jakub, Volkringer Christophe, Henry Natacha, Loiseau Thierry.
    Journal of Fluorine Chemistry, vol. 159, pg. 1-7 (2014) DOI
     
  • The crystal chemistry of uranium carboxylates.
    Loiseau Thierry, Mihalcea Ionut, Henry Natacha, Volkringer Christophe.
    Coordination Chemistry Reviews, vol. 266-267, pg. 69-109 (2014) DOI
     
  • Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules.
    Mihalcea Ionut, Henry Natacha, Loiseau Thierry.
    European Journal of Inorganic Chemistry, vol. 2014, pg. 1322-1332 (2014) DOI
     
  • Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers.
    Mihalcea Ionut, Falaise Clément, Volkringer Christophe, Henry Natacha, Loiseau Thierry.
    Inorganic Chemistry Communications, vol. 44, pg. 63-66 (2014) DOI
     
  • Probing 27Al–13C proximities in metal–organic frameworks using dynamic nuclear polarization enhanced NMR spectroscopy.
    Pourpoint Frédérique, Thankamony Aany Sofia Lilly, Volkringer Christophe, Loiseau Thierry, Trébosc Julien, Aussenac Fabien, Carnevale Diego, Bodenhausen Geoffrey, Vezin Hervé, Lafon Olivier, Amoureux Jean-Paul.
    Chemical Communications, vol. 50, pg. 933 (2014) DOI
     
  • 2013

  • Single-crystal XRD and solid-state NMR structural resolution of a layered fluorinated gallium phosphate: RbGa3(PO4)2(HPO4)F4·C5N2H16·2H2O (MIL-145).
    Martineau Charlotte, Loiseau Thierry, Beitone Lionel, Férey Gérard, Bouchevreau Boris, Taulelle Francis.
    Dalton Trans., vol. 42, pg. 422-431 (2013) DOI
     
  • Synthesis and Characterization of [Mo3S4(NDABu)(HNDABu)2]3-and [Mo3S4(HNDAPr)3]2-Anions as Building Blocks for Organic-Inorganic Hybrid Solids.
    Duval Sylvain, Dumur Frédéric, Guénée Laure, Marrot Jérôme, Simonnet-Jégat Corine, Cadot Emmanuel.
    European Journal of Inorganic Chemistry, vol. 2013, pg. 1149-1156 (2013) DOI
     
  • Synthesis and structural characterization of metal–organic frameworks with the mellitate linker M2(OH)2[C12O12H2]·2H2O (M = Al, Ga, In) MIL-116.
    Volkringer Christophe, Loiseau Thierry, Guillou Nathalie, Férey Gérard, Popov Dmitry, Burghammer Manfred, Riekel Christian.
    Solid State Sciences, vol. 26, pg. 38-44 (2013) DOI
     
  • Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid-State Topotactic Transformation upon Dehydration.
    Olchowka Jakub, Falaise Clément, Volkringer Christophe, Henry Natacha, Loiseau Thierry.
    Chemistry - A European Journal, vol. 19, pg. 2012-2022 (2013) DOI
     
  • Crystal structures of 2,2′:6′,2″-terpyridine uranyl chlorides molecular assemblies and their luminescence signatures.
    Lhoste Jérôme, Henry Natacha, Loiseau Thierry, Guyot Yannick, Abraham Francis.
    Polyhedron, vol. 50, pg. 321-327 (2013) DOI
     
  • Three-Dimensional MOF-Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8).
    Falaise Clément, Volkringer Christophe, Vigier Jean-François, Henry Natacha, Beaurain Arnaud, Loiseau Thierry.
    Chemistry - A European Journal, vol. 19, pg. 5324-5331 (2013) DOI
     
  • Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O.
    Olchowka Jakub, Volkringer Christophe, Henry Natacha, Loiseau Thierry.
    European Journal of Inorganic Chemistry, vol. 2013, pg. 2109-2114 (2013) DOI
     
  • Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U4O4} and Hexanuclear {U6O4(OH)4} Motifs.
    Falaise Clément, Volkringer Christophe, Loiseau Thierry.
    Crystal Growth < Design, vol. 13, pg. 3225-3231 (2013) DOI
     
  • Capture of iodine in highly stable metal–organic frameworks: a systematic study.
    Falaise Clément, Volkringer Christophe, Facqueur Jacques, Bousquet Till, Gasnot Laurent, Loiseau Thierry.
    Chemical Communications, vol. 49, pg. 10320 (2013) DOI
     
  • Isolation of the Large {Actinide}38Poly-oxo Cluster with Uranium.
    Falaise Clément, Volkringer Christophe, Vigier Jean-François, Beaurain Arnaud, Roussel Pascal, Rabu Pierre, Loiseau Thierry.
    Journal of the American Chemical Society, vol. 135, pg. 15678-15681 (2013) DOI